دورية أكاديمية

Chitosan Supports Boosting NiCo 2 O 4 for Catalyzed Urea Electrochemical Removal Application.

التفاصيل البيبلوغرافية
العنوان: Chitosan Supports Boosting NiCo 2 O 4 for Catalyzed Urea Electrochemical Removal Application.
المؤلفون: Alamro FS; Department of Chemistry, College of Science, Princess Nourah Bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi Arabia., Hefnawy MA; Chemistry Department, Faculty of Science, Cairo University, Giza 12613, Egypt., Nafee SS; Physics Department, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia., Al-Kadhi NS; Department of Chemistry, College of Science, Princess Nourah Bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi Arabia., Pashameah RA; Department of Chemistry, Faculty of Applied Science, Umm Al-Qura University, Makkah 24230, Saudi Arabia., Ahmed HA; Chemistry Department, Faculty of Science, Cairo University, Giza 12613, Egypt.; Chemistry Department, College of Sciences, Taibah University, Yanbu 30799, Saudi Arabia., Medany SS; Chemistry Department, Faculty of Science, Cairo University, Giza 12613, Egypt.
المصدر: Polymers [Polymers (Basel)] 2023 Jul 16; Vol. 15 (14). Date of Electronic Publication: 2023 Jul 16.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: MDPI Country of Publication: Switzerland NLM ID: 101545357 Publication Model: Electronic Cited Medium: Internet ISSN: 2073-4360 (Electronic) Linking ISSN: 20734360 NLM ISO Abbreviation: Polymers (Basel) Subsets: PubMed not MEDLINE
أسماء مطبوعة: Original Publication: Basel : MDPI
مستخلص: Currently, wastewater containing high urea levels poses a significant risk to human health. Else, electrocatalytic methodologies have the potential to transform urea present in urea-rich wastewater into hydrogen, thereby contributing towards environmental conservation and facilitating the production of sustainable energy. The characterization of the NiCo 2 O 4 @chitosan catalyst was performed by various analytical techniques, including scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Furthermore, the activity of electrodes toward urea removal was investigated by several electrochemical techniques. As a function of current density, the performance of the modified NiCo 2 O 4 @chitosan surface was employed to remove urea using electrochemical oxidation. Consequently, the current density measurement was 43 mA cm -2 in a solution of 1.0 M urea and 1.0 M KOH. Different kinetic characteristics were investigated, including charge transfer coefficient (α), Tafel slope (29 mV dec -1 ), diffusion coefficient (1.87 × 10 -5 cm 2 s -1 ), and surface coverage 4.29 × 10 -9 mol cm -2 . The electrode showed high stability whereas it lost 10.4% of its initial current after 5 h of urea oxidation.
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فهرسة مساهمة: Keywords: nickel cobaltite; spinel oxide: electrochemical oxidation; urea removal
تواريخ الأحداث: Date Created: 20230729 Latest Revision: 20231102
رمز التحديث: 20231215
مُعرف محوري في PubMed: PMC10384518
DOI: 10.3390/polym15143058
PMID: 37514447
قاعدة البيانات: MEDLINE
الوصف
تدمد:2073-4360
DOI:10.3390/polym15143058