دورية أكاديمية
Gel Biopolymer Electrolytes Based on Saline Water and Seaweed to Support the Large-Scale Production of Sustainable Supercapacitors.
العنوان: | Gel Biopolymer Electrolytes Based on Saline Water and Seaweed to Support the Large-Scale Production of Sustainable Supercapacitors. |
---|---|
المؤلفون: | Santa-Cruz LA; Programa de Pós-Graduação em Ciência de Materiais, Universidade Federal de Pernambuco, Recife, CEP 50740-560, PE, Brazil.; Laboratório de Materiais Nanoestruturados (LMNano), Centro de Tecnologias Estratégicas do Nordeste (CETENE), Recife, CEP 50740-545, PE, Brasil., Mantovi PS; Laboratório de Materiais Eletroativos, Universidade de São Paulo, São Paulo, CEP 05508-900, SP, Brazil., Loguercio LF; Institute of Chemistry, Universidade Federal do Rio Grande do Sul, Rio Grande do Sul, CEP 90650-001, RS, Brazil., Galvão RA; Graduate School of Medicine, Science and Technology, Shinshu University, 380-0928, Nagano, Japan., Navarro M; Programa de Pós-Graduação em Ciência de Materiais, Universidade Federal de Pernambuco, Recife, CEP 50740-560, PE, Brazil., Passos STA; Instituto de química e física, Universidade de Brasília, Brasília, CEP 70904-970, DF, Brazil., Neto BAD; Instituto de química e física, Universidade de Brasília, Brasília, CEP 70904-970, DF, Brazil., Tavares FC; Campus Duque de Caxias, Universidade Federal do Rio de Janeiro, Rio de Janeiro, CEP 25240-005, RJ, Brazil., Torresi RM; Laboratório de Materiais Eletroativos, Universidade de São Paulo, São Paulo, CEP 05508-900, SP, Brazil., Machado G; Laboratório de Materiais Nanoestruturados (LMNano), Centro de Tecnologias Estratégicas do Nordeste (CETENE), Recife, CEP 50740-545, PE, Brasil. |
المصدر: | ChemSusChem [ChemSusChem] 2024 Jan 22; Vol. 17 (2), pp. e202300884. Date of Electronic Publication: 2023 Nov 15. |
نوع المنشور: | Journal Article |
اللغة: | English |
بيانات الدورية: | Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 101319536 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1864-564X (Electronic) Linking ISSN: 18645631 NLM ISO Abbreviation: ChemSusChem Subsets: PubMed not MEDLINE; MEDLINE |
أسماء مطبوعة: | Original Publication: Weinheim : Wiley-VCH |
مستخلص: | Climate change and the demand for clean energy have challenged scientists worldwide to produce/store more energy to reduce carbon emissions. This work proposes a conductive gel biopolymer electrolyte to support the sustainable development of high-power aqueous supercapacitors. The gel uses saline water and seaweed as sustainable resources. Herein, a biopolymer agar-agar, extracted from red algae, is modified to increase gel viscosity up to 17-fold. This occurs due to alkaline treatment and an increase in the concentration of the agar-agar biopolymer, resulting in a strengthened gel with cohesive superfibres. The thermal degradation and agar modification mechanisms are explored. The electrolyte is applied to manufacture sustainable and flexible supercapacitors with satisfactory energy density (0.764 Wh kg -1 ) and power density (230 W kg -1 ). As an electrolyte, the aqueous gel promotes a long device cycle life (3500 cycles) for 1 A g -1 , showing good transport properties and low cost of acquisition and enabling the supercapacitor to be manufactured outside a glove box. These features decrease the cost of production and favor scale-up. To this end, this work provides eco-friendly electrolytes for the next generation of flexible energy storage devices. (© 2023 Wiley-VCH GmbH.) |
References: | L. De La Peña, R. Guo, X. Cao, X. Ni, W. Zhang, Resour. Conserv. Recycl. 2022, 177, 105957. T. Yan, Y. Zou, X. Zhang, D. Li, X. Guo, D. Yang, ACS Appl. Mater. Interfaces 2021, 13, 9856-9864. P. Jiang, Y. Van Fan, J. J. Klemeš, Appl. Energy 2021, 285, 116441. T. Xu, K. Liu, N. Sheng, M. Zhang, W. Liu, H. Liu, L. Dai, X. Zhang, C. Si, H. Du, K. Zhang, Energy Storage Mater. 2022, 48, 244-262. P. Chen, F. Xie, F. Tang, T. McNally, Carbohydr. Polym. 2021, 253, 117231. P. R. Kasturi, H. Ramasamy, D. Meyrick, Y. Sung Lee, R. Kalai Selvan, J. Colloid Interface Sci. 2019, 554, 142-156. R. Geyer, J. R. Jambeck, K. L. Law, Sci. Adv. 2017, 3, DOI 10.1126/sciadv.1700782. N. Lima, A. C. Baptista, B. M. M. Faustino, S. Taborda, A. Marques, I. Ferreira, Sci. Rep. 2020, 10, 7703. A. Rag, S. M. Selvakumar, S. De, S. Chidangil, S. Bhat, Mater. Today: Proc. 2022, 48, 365-370. D. Xiao, Q. Wu, X. Liu, Q. Dou, L. Liu, B. Yang, H. Yu, ChemElectroChem 2019, 6, 439-443. Y. Zhao, Y. Alsaid, B. Yao, Y. Zhang, B. Zhang, N. Bhuskute, S. Wu, X. He, Adv. Funct. Mater. 2020, 30, 1909133. T. Ye, Y. Zou, W. Xu, T. Zhan, J. Sun, Y. Xia, X. Zhang, D. Yang, J. Power Sources 2020, 475, 228688. B. Zhang, C. Zhang, W. Yuan, O. Yang, Y. Liu, L. He, Y. Hu, L. Zhou, J. Wang, Z. L. Wang, ACS Appl. Mater. Interfaces 2022, 14, 9046-9056. F. G. Torres, G. E. De-la-Torre, Carbohydr. Polym. Technol. Appl. 2021, 2, 100023. M. Z. Iqbal, S. Zakar, S. S. Haider, J. Electroanal. Chem. 2020, 858, 113793. R. Ramachandran, F. Wang, Supercapacitors - Theor. Pract. Solut., InTech 2018. Advances in Supercapacitor and Supercapattery, Elsevier 2021. J. Menzel, E. Frąckowiak, K. Fic, Electrochim. Acta 2020, 332, 135435. I. Malagurski, S. Levic, A. Nesic, M. Mitric, V. Pavlovic, S. Dimitrijevic-Brankovic, Carbohydr. Polym. 2017, 175, 55-62. S. Yarnpakdee, S. Benjakul, P. Kingwascharapong, Food Hydrocolloids 2015, 51, 217-226. Z. M. Al-Nahdi, A. Al-Alawi, I. Al-Marhobi, J. Mar. Biol. 2019, 2019, 1-10. L. Shahnaz, H. Shehnaz, A. Haider, Bangladesh J. Bot. 2019, 48, 925-932. M. Martínez-Sanz, L. G. Gómez-Mascaraque, A. R. Ballester, A. Martínez-Abad, A. Brodkorb, A. López-Rubio, Algal Res. 2019, 38, 101420. E. Gómez-Ordóñez, P. Rupérez, Food Hydrocolloids 2011, 25, 1514-1520. E. A. El-hefian, M. M. Nasef, A. H. Yahaya, E-J. Chem. 2012, 9, 1431-1439. G. Boopathi, S. Pugalendhi, S. Selvasekarapandian, M. Premalatha, S. Monisha, G. Aristatil, Ionics 2017, 23, 2781-2790. M. Watase, K. Nishinari, Rheol. Acta 1981, 20, 155-162. M. Atef, M. Rezaei, R. Behrooz, Food Hydrocolloids 2015, 45, 150-157. P. Kanmani, J.-W. Rhim, Carbohydr. Polym. 2014, 102, 708-716. L. Liu, R. Cai, Y. Wang, G. Tao, L. Ai, P. Wang, M. Yang, H. Zuo, P. Zhao, H. He, Int. J. Mol. Sci. 2018, 19, 2875. M. Tako, Y. Tamaki, T. Teruya, Y. Takeda, Food Nutr. Sci. 2014, 05, 280-291. K. Nishinari, M. Watase, Carbohydr. Polym. 1983, 3, 39-52. C.-W. Lien, B. Vedhanarayanan, J.-H. Chen, J.-Y. Lin, H.-H. Tsai, L.-D. Shao, T.-W. Lin, Chem. Eng. J. 2021, 405, 126706. D. A. C. da Silva, M. J. Pinzón, C. A. Messias, E. E. Fileti, A. Pascon, D. V. Franco, L. M. Da Silva, H. G. Zanin, Mater Adv 2022, 3, 611-623. K. C. Labropoulos, D. E. Niesz, S. C. Danforth, P. G. Kevrekidis, Carbohydr. Polym. 2002, 50, 407-415. X. Zang, C. Shen, M. Sanghadasa, L. Lin, ChemElectroChem 2019, 6, 976-988. S. Oveisi, Z. Khakpour, M. A. Faghihi-sani, M. Kazemzad, J. Sol-Gel Sci. Technol. 2021, 97, 581-592. T. dos S. Costa, A. M. da C. Rodrigues, R. da S. Pena, Food Sci. Technol. 2019, 39, 684-690. B. Mao, T. Divoux, P. Snabre, J. Rheol. 2016, 60, 473-489. V. M. P. Vieira, L. L. Hay, D. K. Smith, Chem. Sci. 2017, 8, 6981-6990. V. L. Martins, P. S. Mantovi, R. M. Torresi, Electrochim. Acta 2021, 372, 137854. V. L. Martins, H. R. Neves, I. E. Monje, M. M. Leite, P. F. M. De Oliveira, R. M. Antoniassi, S. Chauque, W. G. Morais, E. C. Melo, T. T. Obana, B. L. Souza, R. M. Torresi, An. Acad. Bras. Cienc. 2020, 92, DOI 10.1590/0001-3765202020200796. Y. Gong, D. Li, C. Luo, Q. Fu, C. Pan, Green Chem. 2017, 19, 4132-4140. L. A. Santa-Cruz, G. Machado, A. A. Vicente, T. F. C. Hermenegildo, T. F. A. Santos, Int. J. Miner. Metall. Mater. 2019, 26, 710-721. L. A. Santa-Cruz, I. J. Marques, S. L. Urtiga Filho, T. F. C. Hermenegildo, T. F. A. Santos, Metallogr. Microstruct. Anal. 2019, 8, 32-44. X. Liu, R. Mi, L. Yuan, F. Yang, Z. Fu, C. Wang, Y. Tang, Front. Chem. 2018, 6, DOI 10.3389/fchem.2018.00475. P. Simon, Y. Gogotsi, Nat. Mater. 2008, 7, 845-854. R. Vinodh, Y. Sasikumar, H.-J. Kim, R. Atchudan, M. Yi, J. Ind. Eng. Chem. 2021, 104, 155-171. S. N. F. Yusuf, A. K. Arof, Polym. Electrolytes, Wiley 2020, pp. 137-186. G. Landi, L. La Notte, A. L. Palma, A. Sorrentino, M. G. Maglione, G. Puglisi, Nanomaterials 2021, 12, 46. M. Sandhiya, Vivekanand, S. Suresh Balaji, M. Sathish, ACS Appl. Energy Mater. 2020, 3, 11368-11377. |
معلومات مُعتمدة: | IBPG-0846-1.06/19 FACEPE; 424116/2018-9 CNPq; 308504/2017-8 CNPq; 442477/2019-8 CNPq; 88887.146289/2017-00 CAPES; National System of Laboratories in Nanotechnology (SisNANO) at CETENE |
فهرسة مساهمة: | Keywords: aqueous electrolyte; energy storage; gel biopolymer electrolyte •, sustainable; supercapacitor |
تواريخ الأحداث: | Date Created: 20230914 Latest Revision: 20240130 |
رمز التحديث: | 20240131 |
DOI: | 10.1002/cssc.202300884 |
PMID: | 37707501 |
قاعدة البيانات: | MEDLINE |
تدمد: | 1864-564X |
---|---|
DOI: | 10.1002/cssc.202300884 |