دورية أكاديمية
أعرض في EDS

Tailoring Interlayer Charge Transfer Dynamics in 2D Perovskites with Electroactive Spacer Molecules.

التفاصيل البيبلوغرافية
العنوان: Tailoring Interlayer Charge Transfer Dynamics in 2D Perovskites with Electroactive Spacer Molecules.
المؤلفون: Boeije Y; Department of Chemical Engineering and Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, U.K.; Department of Physics, Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, U.K., Van Gompel WTM; Institute for Materials Research (IMO-IMOMEC), Hybrid Materials Design (HyMaD), Hasselt University, Martelarenlaan 42, B-3500 Hasselt, Belgium., Zhang Y; Department of Physics, Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, U.K.; Cambridge Graphene Centre, Department of Engineering, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0FA, U.K., Ghosh P; Department of Physics, Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, U.K., Zelewski SJ; Department of Chemical Engineering and Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, U.K.; Department of Physics, Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, U.K.; Department of Semiconductor Materials Engineering, Faculty of Fundamental Problems of Technology, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland., Maufort A; Institute for Materials Research (IMO-IMOMEC), Hybrid Materials Design (HyMaD), Hasselt University, Martelarenlaan 42, B-3500 Hasselt, Belgium., Roose B; Department of Chemical Engineering and Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, U.K., Ooi ZY; Department of Chemical Engineering and Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, U.K., Chowdhury R; Department of Physics, Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, U.K., Devroey I; Institute for Materials Research (IMO-IMOMEC), Hybrid Materials Design (HyMaD), Hasselt University, Martelarenlaan 42, B-3500 Hasselt, Belgium., Lenaers S; Institute for Materials Research (IMO-IMOMEC), Hybrid Materials Design (HyMaD), Hasselt University, Martelarenlaan 42, B-3500 Hasselt, Belgium., Tew A; Department of Physics, Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, U.K., Dai L; Department of Chemical Engineering and Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, U.K.; Department of Physics, Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, U.K., Dey K; Department of Physics, Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, U.K., Salway H; Department of Chemical Engineering and Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, U.K., Friend RH; Department of Physics, Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, U.K., Sirringhaus H; Department of Physics, Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, U.K., Lutsen L; Institute for Materials Research (IMO-IMOMEC), Hybrid Materials Design (HyMaD), Hasselt University, Martelarenlaan 42, B-3500 Hasselt, Belgium., Vanderzande D; Institute for Materials Research (IMO-IMOMEC), Hybrid Materials Design (HyMaD), Hasselt University, Martelarenlaan 42, B-3500 Hasselt, Belgium., Rao A; Department of Physics, Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, U.K., Stranks SD; Department of Chemical Engineering and Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, U.K.; Department of Physics, Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, U.K.
المصدر: Journal of the American Chemical Society [J Am Chem Soc] 2023 Oct 04; Vol. 145 (39), pp. 21330-21343. Date of Electronic Publication: 2023 Sep 22.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-5126 (Electronic) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: PubMed not MEDLINE; MEDLINE
أسماء مطبوعة: Publication: Washington, DC : American Chemical Society
Original Publication: Easton, Pa. [etc.]
مستخلص: The family of hybrid organic-inorganic lead-halide perovskites are the subject of intense interest for optoelectronic applications, from light-emitting diodes to photovoltaics to X-ray detectors. Due to the inert nature of most organic molecules, the inorganic sublattice generally dominates the electronic structure and therefore the optoelectronic properties of perovskites. Here, we use optically and electronically active carbazole-based Cz-C i molecules, where C i indicates an alkylammonium chain and i indicates the number of CH 2 units in the chain, varying from 3 to 5, as cations in the two-dimensional (2D) perovskite structure. By investigating the photophysics and charge transport characteristics of (Cz-C i ) 2 PbI 4 , we demonstrate a tunable electronic coupling between the inorganic lead-halide and organic layers. The strongest interlayer electronic coupling was found for (Cz-C 3 ) 2 PbI 4 , where photothermal deflection spectroscopy results remarkably reveal an organic-inorganic charge transfer state. Ultrafast transient absorption spectroscopy measurements demonstrate ultrafast hole transfer from the photoexcited lead-halide layer to the Cz-C i molecules, the efficiency of which increases by varying the chain length from i = 5 to i = 3. The charge transfer results in long-lived carriers (10-100 ns) and quenched emission, in stark contrast to the fast (sub-ns) and efficient radiative decay of bound excitons in the more conventional 2D perovskite (PEA) 2 PbI 4 , in which phenylethylammonium (PEA) acts as an inert spacer. Electrical charge transport measurements further support enhanced interlayer coupling, showing increased out-of-plane carrier mobility from i = 5 to i = 3. This study paves the way for the rational design of 2D perovskites with combined inorganic-organic electronic properties through the wide range of functionalities available in the world of organics.
References: Chem Sci. 2023 May 15;14(22):6052-6058. (PMID: 37293640)
J Am Chem Soc. 2020 Nov 18;142(46):19705-19714. (PMID: 33147413)
J Phys Chem Lett. 2020 Mar 19;11(6):2247-2255. (PMID: 32119553)
Adv Mater. 2014 Apr 23;26(16):2533-9. (PMID: 24574091)
J Am Chem Soc. 2018 Jun 13;140(23):7313-7323. (PMID: 29869499)
J Am Chem Soc. 2020 Jul 1;142(26):11486-11496. (PMID: 32492336)
Nat Mater. 2014 Jan;13(1):63-8. (PMID: 24240240)
J Chem Phys. 2020 Jan 31;152(4):044711. (PMID: 32007060)
Nat Nanotechnol. 2020 Dec;15(12):969-985. (PMID: 33277622)
Nat Mater. 2019 May;18(5):459-464. (PMID: 30936478)
Science. 2017 Mar 24;355(6331):1288-1292. (PMID: 28280250)
Chem Sci. 2018 Sep 25;9(48):8975-8981. (PMID: 30627411)
Chem Rev. 2019 Oct 23;119(20):11007-11019. (PMID: 31496228)
Nano Lett. 2016 May 11;16(5):3335-40. (PMID: 27100910)
Phys Rev Lett. 2008 Jun 27;100(25):257401. (PMID: 18643701)
Opt Lett. 2014 Jul 15;39(14):4112-5. (PMID: 25121664)
Nano Lett. 2021 Jan 13;21(1):405-413. (PMID: 33337888)
Science. 2021 Feb 5;371(6529):636-640. (PMID: 33542138)
J Am Chem Soc. 2019 Jul 10;141(27):10661-10676. (PMID: 31246449)
Adv Sci (Weinh). 2018 Nov 24;6(2):1801628. (PMID: 30693191)
Nat Mater. 2020 Nov;19(11):1224-1229. (PMID: 32541936)
Inorg Chem. 2005 Jun 27;44(13):4699-705. (PMID: 15962978)
Nat Commun. 2017 May 04;8:15251. (PMID: 28469178)
J Am Chem Soc. 2019 Apr 10;141(14):5972-5979. (PMID: 30882210)
Adv Mater. 2021 Aug;33(32):e2100791. (PMID: 34219297)
J Am Chem Soc. 2015 Jun 24;137(24):7843-50. (PMID: 26020457)
Nat Commun. 2017 Nov 3;8(1):1300. (PMID: 29101381)
Adv Mater. 2018 Nov;30(48):e1802041. (PMID: 30199108)
Phys Rev B Condens Matter. 1990 Dec 15;42(17):11099-11107. (PMID: 9995391)
Nature. 2021 Sep;597(7878):666-671. (PMID: 34588666)
Chem Rev. 2021 Feb 24;121(4):2230-2291. (PMID: 33476131)
J Chem Phys. 2023 Jan 7;158(1):014202. (PMID: 36610952)
Rev Sci Instrum. 2007 Jan;78(1):013705. (PMID: 17503926)
ACS Energy Lett. 2021 Mar 12;6(3):1087-1094. (PMID: 33869770)
J Am Chem Soc. 2021 Dec 1;143(47):19901-19908. (PMID: 34788034)
J Am Chem Soc. 2004 May 19;126(19):6035-42. (PMID: 15137768)
Adv Sci (Weinh). 2018 Aug 13;5(10):1800664. (PMID: 30356921)
Nat Commun. 2020 May 11;11(1):2344. (PMID: 32393785)
J Phys Chem Lett. 2021 Mar 18;12(10):2528-2535. (PMID: 33683137)
Nat Commun. 2018 Jun 8;9(1):2254. (PMID: 29884900)
Sci Adv. 2021 Aug 4;7(32):. (PMID: 34348902)
J Phys Chem Lett. 2020 Oct 15;11(20):8565-8572. (PMID: 32975424)
Nat Commun. 2015 Mar 04;6:6501. (PMID: 25735188)
J Am Chem Soc. 2019 Oct 2;141(39):15577-15585. (PMID: 31525969)
Sci Adv. 2018 Jan 12;4(1):eaao3104. (PMID: 29340303)
Nat Chem. 2019 Dec;11(12):1151-1157. (PMID: 31712613)
Science. 2013 Oct 18;342(6156):341-4. (PMID: 24136964)
Adv Mater. 2018 May;30(20):e1800691. (PMID: 29569287)
Chem Rev. 2019 Mar 13;119(5):3140-3192. (PMID: 30638375)
Nat Commun. 2020 Jun 1;11(1):2712. (PMID: 32483150)
J Phys Chem Lett. 2018 Mar 15;9(6):1434-1447. (PMID: 29481089)
J Am Chem Soc. 2017 Dec 27;139(51):18632-18639. (PMID: 29155583)
J Phys Chem Lett. 2020 Feb 6;11(3):824-830. (PMID: 31944771)
Nat Mater. 2018 Jun;17(6):550-556. (PMID: 29760510)
Nature. 2013 Aug 22;500(7463):435-9. (PMID: 23925118)
ACS Nano. 2018 Apr 24;12(4):3321-3332. (PMID: 29481060)
Nat Chem. 2020 Aug;12(8):672-682. (PMID: 32632185)
Inorg Chem. 2017 Aug 7;56(15):9291-9302. (PMID: 28749133)
J Phys Chem Lett. 2018 Jun 21;9(12):3416-3424. (PMID: 29870266)
J Phys Chem C Nanomater Interfaces. 2018 Aug 2;122(30):17118-17122. (PMID: 30093930)
Chem Commun (Camb). 2019 Feb 21;55(17):2481-2484. (PMID: 30734783)
تواريخ الأحداث: Date Created: 20230922 Latest Revision: 20231010
رمز التحديث: 20240628
مُعرف محوري في PubMed: PMC10557141
DOI: 10.1021/jacs.3c05974
PMID: 37738152
قاعدة البيانات: MEDLINE
الوصف
تدمد:1520-5126
DOI:10.1021/jacs.3c05974