دورية أكاديمية
Design of a New Phthalocyanine-Based Ion-Imprinted Polymer for Selective Lithium Recovery from Desalination Plant Reverse Osmosis Waste.
العنوان: | Design of a New Phthalocyanine-Based Ion-Imprinted Polymer for Selective Lithium Recovery from Desalination Plant Reverse Osmosis Waste. |
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المؤلفون: | Jamoussi B; Department of Environment, Faculty of Environmental Sciences, King Abdulaziz University, Jeddah 21589, Saudi Arabia., Chakroun R; Department of Environment, Faculty of Environmental Sciences, King Abdulaziz University, Jeddah 21589, Saudi Arabia., Al-Mur BA; Department of Environment, Faculty of Environmental Sciences, King Abdulaziz University, Jeddah 21589, Saudi Arabia., Halawani RF; Department of Environment, Faculty of Environmental Sciences, King Abdulaziz University, Jeddah 21589, Saudi Arabia., Aloufi FA; Department of Environment, Faculty of Environmental Sciences, King Abdulaziz University, Jeddah 21589, Saudi Arabia., Chaabani A; Department of Hydrology and Water Resources Management, Faculty of Environmental Sciences, King Abdulaziz University, Jeddah 21589, Saudi Arabia., Aljohani NS; Department of Environment, Faculty of Environmental Sciences, King Abdulaziz University, Jeddah 21589, Saudi Arabia.; Saline Water Conversion Corporation, Riyadh 11432, Saudi Arabia. |
المصدر: | Polymers [Polymers (Basel)] 2023 Sep 21; Vol. 15 (18). Date of Electronic Publication: 2023 Sep 21. |
نوع المنشور: | Journal Article |
اللغة: | English |
بيانات الدورية: | Publisher: MDPI Country of Publication: Switzerland NLM ID: 101545357 Publication Model: Electronic Cited Medium: Internet ISSN: 2073-4360 (Electronic) Linking ISSN: 20734360 NLM ISO Abbreviation: Polymers (Basel) |
أسماء مطبوعة: | Original Publication: Basel : MDPI |
مستخلص: | In this study, a novel technique is introduced that involves the combination of an ion-imprinted polymer and solid-phase extraction to selectively adsorb lithium ions from reverse osmosis brine. In the process of synthesizing ion-imprinted polymers, phthalocyanine acrylate acted as the functional monomer responsible for lithium chelation. The structural and morphological characteristics of the molecularly imprinted polymers and non-imprinted polymers were assessed using Fourier transform infrared spectroscopy and scanning electron microscopy. The adsorption data for Li on an ion-imprinted polymer showed an excellent fit to the Langmuir isotherm, with a maximum adsorption capacity (Qm) of 3.2 mg·g -1 . Comprehensive chemical analyses revealed a significant Li concentration with a higher value of 45.36 mg/L. Through the implementation of a central composite design approach, the adsorption and desorption procedures were systematically optimized by varying the pH, temperature, sorbent mass, and elution volume. This systematic approach allowed the identification of the most efficient operating conditions for extracting lithium from seawater reverse osmosis brine using ion-imprinted polymer-solid-phase extraction. The optimum operating conditions for the highest efficiency of adsorbing Li + were determined to be a pH of 8.49 and a temperature of 45.5 °C. The efficiency of ion-imprinted polymer regeneration was evaluated through a cycle of the adsorption-desorption process, which resulted in Li recoveries of up to 80%. The recovery of Li from the spiked brine sample obtained from the desalination plant reverse osmosis waste through the ion-imprinted polymer ranged from 62.8% to 71.53%. |
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معلومات مُعتمدة: | G:344-155-1443 King Abdulaziz University |
فهرسة مساهمة: | Keywords: Li recovery; central composite design (CCD); desalination plant reverse osmosis waste; ion-imprinted polymer (IIP); response surface methodology (RSM); solid-phase extraction (SPE) |
تواريخ الأحداث: | Date Created: 20230928 Latest Revision: 20231003 |
رمز التحديث: | 20231215 |
مُعرف محوري في PubMed: | PMC10537805 |
DOI: | 10.3390/polym15183847 |
PMID: | 37765702 |
قاعدة البيانات: | MEDLINE |
تدمد: | 2073-4360 |
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DOI: | 10.3390/polym15183847 |