دورية أكاديمية
أعرض في EDS

Visible light activated energy storage in solid-state Azo-BF 2 switches.

التفاصيل البيبلوغرافية
العنوان: Visible light activated energy storage in solid-state Azo-BF 2 switches.
المؤلفون: Qiu Q; Department of Chemistry, Brandeis University 415 South Street Waltham MA 02453 USA gracehan@brandeis.edu., Qi Q; Department of Chemistry, Dartmouth College Hanover NH 03755 USA ivan.aprahamian@dartmouth.edu., Usuba J; Department of Chemistry, Brandeis University 415 South Street Waltham MA 02453 USA gracehan@brandeis.edu., Lee K; Department of Chemistry, Brandeis University 415 South Street Waltham MA 02453 USA gracehan@brandeis.edu., Aprahamian I; Department of Chemistry, Dartmouth College Hanover NH 03755 USA ivan.aprahamian@dartmouth.edu., Han GGD; Department of Chemistry, Brandeis University 415 South Street Waltham MA 02453 USA gracehan@brandeis.edu.
المصدر: Chemical science [Chem Sci] 2023 Sep 26; Vol. 14 (41), pp. 11359-11364. Date of Electronic Publication: 2023 Sep 26 (Print Publication: 2023).
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 101545951 Publication Model: eCollection Cited Medium: Print ISSN: 2041-6520 (Print) Linking ISSN: 20416520 NLM ISO Abbreviation: Chem Sci Subsets: PubMed not MEDLINE
أسماء مطبوعة: Original Publication: Cambridge, UK : Royal Society of Chemistry, [2010]-
مستخلص: We present here a group of Azo-BF 2 photoswitches that store and release energy in response to visible light irradiation. Unmodified Azo-BF 2 switches have a planar structure with a large π-conjugation system, which hinders E-Z isomerization when in a compacted state. To address this challenge, we modified the switches with one or two aliphatic groups, which altered the intermolecular interactions and arrangement of the photochromes in the solid state. The derivative with two substituents exhibited a non-planar configuration that provided particularly large conformational freedom, allowing for efficient isomerization in the solid phase. Our discovery highlights the potential of using double aliphatic functionalization as a promising approach to facilitate solid-state switching of large aromatic photoswitches. This finding opens up new possibilities for exploring various photoswitch candidates for molecular solar thermal energy storage applications.
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
References: J Am Chem Soc. 2020 May 13;142(19):8688-8695. (PMID: 32319773)
ChemSusChem. 2023 Sep 22;16(18):e202300582. (PMID: 37278140)
J Am Chem Soc. 2018 Jun 20;140(24):7611-7622. (PMID: 29807417)
Angew Chem Int Ed Engl. 2020 Nov 23;59(48):21663-21670. (PMID: 33462976)
J Org Chem. 2017 Oct 6;82(19):10398-10407. (PMID: 28853882)
J Am Chem Soc. 2018 Aug 22;140(33):10425-10429. (PMID: 30074782)
J Am Chem Soc. 2017 Jan 25;139(3):1037-1040. (PMID: 28072532)
ACS Appl Mater Interfaces. 2020 Jul 15;12(28):32054-32060. (PMID: 32551520)
Methods. 2002 Sep;28(1):4-13. (PMID: 12231182)
Angew Chem Int Ed Engl. 2015 Sep 21;54(39):11338-49. (PMID: 26096635)
Acc Chem Res. 2020 Aug 18;53(8):1478-1487. (PMID: 32662627)
Chemistry. 2023 Apr 6;29(20):e202300268. (PMID: 36786211)
Chemphyschem. 2016 Sep 19;17(18):2824-38. (PMID: 27324614)
Acc Chem Res. 2020 Nov 17;53(11):2600-2610. (PMID: 32969638)
Org Lett. 2015 Mar 20;17(6):1517-20. (PMID: 25760939)
ACS Appl Mater Interfaces. 2022 Aug 10;14(31):35623-35634. (PMID: 35916069)
J Am Chem Soc. 2014 Sep 24;136(38):13190-3. (PMID: 25222380)
J Am Chem Soc. 2017 Oct 25;139(42):15060-15067. (PMID: 28944664)
J Am Chem Soc. 2022 Jul 20;144(28):12627-12631. (PMID: 35801820)
Angew Chem Int Ed Engl. 2010 Nov 15;49(47):8926-9. (PMID: 20949567)
Angew Chem Int Ed Engl. 2015 Nov 2;54(45):13436-9. (PMID: 26350759)
Beilstein J Org Chem. 2018 May 29;14:1238-1243. (PMID: 29977392)
J Chem Phys. 2021 Nov 14;155(18):184105. (PMID: 34773961)
Angew Chem Int Ed Engl. 2021 Apr 26;60(18):10219-10227. (PMID: 33503292)
Chemistry. 2018 Jun 18;24(34):8639-8647. (PMID: 29601098)
J Am Chem Soc. 2020 Jul 15;142(28):12256-12264. (PMID: 32551567)
Nanomicro Lett. 2022 Jun 29;14(1):138. (PMID: 35767090)
J Am Chem Soc. 2012 Sep 19;134(37):15221-4. (PMID: 22954379)
Chempluschem. 2019 Aug;84(8):1145-1148. (PMID: 31943965)
Dalton Trans. 2016 Jun 7;45(21):8740-4. (PMID: 27109432)
Chemistry. 2022 Feb 24;28(12):e202104284. (PMID: 35025129)
J Am Chem Soc. 2017 Jan 25;139(3):1261-1274. (PMID: 28009517)
تواريخ الأحداث: Date Created: 20231027 Latest Revision: 20231028
رمز التحديث: 20231215
مُعرف محوري في PubMed: PMC10599475
DOI: 10.1039/d3sc03465h
PMID: 37886079
قاعدة البيانات: MEDLINE
الوصف
تدمد:2041-6520
DOI:10.1039/d3sc03465h