دورية أكاديمية
أعرض في EDS

Important role of pore-filling mechanism in separating naproxen from water by micro-mesoporous carbonaceous material.

التفاصيل البيبلوغرافية
العنوان: Important role of pore-filling mechanism in separating naproxen from water by micro-mesoporous carbonaceous material.
المؤلفون: Arslan Y; Faculty of Arts and Science, Nanoscience and Nanotechnology Department, Burdur Mehmet Akif Ersoy University, Burdur, Turkey., Tomul F; Faculty of Arts and Science, Chemistry Department, Burdur Mehmet Akif Ersoy University, Burdur, Turkey., Kınaytürk NK; Faculty of Arts and Science, Nanoscience and Nanotechnology Department, Burdur Mehmet Akif Ersoy University, Burdur, Turkey., Dong NT; Institute of Environmental Technology, Vietnam Academy of Science and Technology, Hanoi, Vietnam., Trak D; Faculty of Arts and Science, Chemistry Department, Burdur Mehmet Akif Ersoy University, Burdur, Turkey., Kabak B; Faculty of Arts and Science, Chemistry Department, Burdur Mehmet Akif Ersoy University, Burdur, Turkey., Tran HN; Center for Energy and Environmental Materials, Institute of Fundamental and Applied Sciences, Duy Tan University, Ho Chi Minh, Vietnam.; Faculty of Environmental and Chemical Engineering, Duy Tan University, Da Nang, Vietnam.
المصدر: Water environment research : a research publication of the Water Environment Federation [Water Environ Res] 2024 Jan; Vol. 96 (1), pp. e10966.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Wiley Subscription Services on behalf of The Water Environment Foundation Country of Publication: United States NLM ID: 9886167 Publication Model: Print Cited Medium: Internet ISSN: 1554-7531 (Electronic) Linking ISSN: 10614303 NLM ISO Abbreviation: Water Environ Res Subsets: MEDLINE
أسماء مطبوعة: Publication: Hoboken, NJ : Wiley Subscription Services on behalf of The Water Environment Foundation
Original Publication: Alexandria, VA : The Federation, c1992-
مواضيع طبية MeSH: Water*/chemistry , Water Pollutants, Chemical*/chemistry, Naproxen ; Sodium Chloride ; Hydrogen-Ion Concentration ; Thermodynamics ; Adsorption ; Kinetics
مستخلص: Commercial micro-mesoporous carbonaceous material (MCM; 56.8% mesopores) was applied for investigating the removal phenomenon of naproxen drug in aqueous solutions through batch adsorption experiments. Results demonstrated that the adsorption capacity of MCM to naproxen was slightly affected by different pH eq (2.0-11) and ionic strength (0-1 M NaCl). Adsorption kinetics, isotherms, thermodynamics, and mechanisms were evaluated at pH 7.0. Adsorption kinetics indicated the rate constants for adsorption (0.2 × 10 -3  L/(mg × min) and desorption (0.076/min) and the adsorption equilibrium constant (2.6 × 10 -3  L/mg). Adsorption isotherm showed that MCM exhibited a high-affinity adsorption capacity to naproxen (even at low concentrations) and its Langmuir maximum adsorption capacity (Q max ) was 252.7 mg/g at 25°C. Adsorption thermodynamics proved that the adsorption process was endothermic and physisorption (ΔH° = 9.66 kJ/mol). The analysis result of pore size distribution demonstrated that the internal pore structure of MCM was appropriate for adsorbing naproxen molecules. Pore-filing mechanism (pore diffusion phenomenon) was confirmed by a considerable decrease in BET-surface area (585 m 2 /g) and total pore volume (0.417 cm 3 /g) of MCM after adsorbing naproxen (~1000 mg/L and pH 7.0) at 5 min (341 and 0.256), 60 min (191 and 0.205), 120 min (183 and 0.193), 360 min (144 and 0.175), and 24 h (71.6 m 2 /g and 0.123 cm 3 /g, respectively). The pore diffusion occurred rapidly (even at the initial adsorption period of 5 min). The FTIR technique was applied to identify the existence of C-H···π and n-π interaction. π-π interaction (evaluated through I D /I G ratio and C=C band) played a minor contribution in adsorption mechanisms. The I D /I G ratio (determined by the Raman technique) of MCM before adsorption (1.195) was similar to that after adsorption (1.190), and the wavenumber (C=C band; its FTIR spectrum) slightly shifted from 1638 to 1634 cm -1 after adsorption. A decrease in the Q max value of MCM from 249 to 217 (H 2 O 2 -oxidized MCM) or to 224 mg/g (HNO 3 -oxidized MCM) confirmed the presence of π-π interaction. Electrostatic attraction was a minor contribution. MCM can serve as a promising material for removing naproxen from water environment through a pore-filling mechanism. PRACTITIONER POINTS: Pore-filling mechanism was proposed by comparing textural properties of MCM before and after adsorbing naproxen. C-H···π and n-π interactions were identified via FTIR technique. π-π interaction was observed by FTIR and Raman techniques. Oxidation of MCM with HNO 3 or H 2 O 2 was a helpful method to explore π-π interaction. Electrostatic attraction was explained through studies: effects of pH and NaCl along with desorption.
(© 2024 Water Environment Federation.)
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فهرسة مساهمة: Keywords: activated carbon; adsorption; emerging pollutant; pore diffusion; surface area; water treatment
المشرفين على المادة: 059QF0KO0R (Water)
57Y76R9ATQ (Naproxen)
451W47IQ8X (Sodium Chloride)
0 (Water Pollutants, Chemical)
تواريخ الأحداث: Date Created: 20240116 Date Completed: 20240117 Latest Revision: 20240124
رمز التحديث: 20240125
DOI: 10.1002/wer.10966
PMID: 38226502
قاعدة البيانات: MEDLINE
الوصف
تدمد:1554-7531
DOI:10.1002/wer.10966