Ultrasensitive Eu-Based MOF Luminescence Sensor for Clenbuterol Visible Recognition.

التفاصيل البيبلوغرافية
العنوان:	Ultrasensitive Eu-Based MOF Luminescence Sensor for Clenbuterol Visible Recognition.
المؤلفون:	Zhang X; College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, P. R. China.; State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization, Baotou Research Institute of Rare Earths, Baotou 014030, P. R. China., Ding W; College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, P. R. China., Jiao C; College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, P. R. China., Kang X; College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, P. R. China., Liu Z; College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, P. R. China.
المصدر:	Inorganic chemistry [Inorg Chem] 2024 Feb 19; Vol. 63 (7), pp. 3383-3392. Date of Electronic Publication: 2024 Feb 05.
نوع المنشور:	Journal Article
اللغة:	English
بيانات الدورية:	Publisher: American Chemical Society Country of Publication: United States NLM ID: 0366543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-510X (Electronic) Linking ISSN: 00201669 NLM ISO Abbreviation: Inorg Chem Subsets: MEDLINE
أسماء مطبوعة:	Original Publication: [Easton, Pa.] American Chemical Society.
مواضيع طبية MeSH:	Clenbuterol*, Animals ; Swine ; Luminescence ; Thiazolidines
مستخلص:	Clenbuterol (CLB) as an illegal feed additive may cause a great security risk to food safety. However, convenient and efficient detection means for CLB in practical application remain a formidable challenge. Herein, a stable Eu-based organic framework {[H 2 N(CH 3 ) 2 ] 2 [Eu 2 (ttca) 2 ]·H 2 O} n (compound 1 ) (H 4 ttca = [1,1':2',1″-terphenyl]-4,4',4″,5'-tetracarboxylic acid) has been harvested, exhibiting excellent chemical stability and thermal stability. Luminescence investigation reveals that compound 1 can sensitively and selectively detect CLB without being affected by different components from simulated serum and urine (limit detection: 22.7 nM). Furthermore, sensor 1 can also be applicable to CLB recognition in real swine feeds, presenting excellent anti-interference performance. The good cyclicity of compound 1 endows CLB determination with many advantages: low cost, high stability, and simplicity. Importantly, in view of the indication of the luminescence color (red to blue), test membranes were fabricated and employed for convenient and fast CLB detection, providing a valuable scheme for the visual monitoring of CLB in meat products. This work enriches rare earth metal compounds and luminescence sensor portfolios and breaks the concentration record (nM) for detecting CLB compared with reported complex materials, providing an effective monitoring platform for CLB visually.
المشرفين على المادة:	XTZ6AXU7KN (Clenbuterol) 20933-67-9 (2-thioxo-4-thiazolidinecarboxylic acid) 0 (Thiazolidines)
تواريخ الأحداث:	Date Created: 20240205 Date Completed: 20240220 Latest Revision: 20240220
رمز التحديث:	20240220
DOI:	10.1021/acs.inorgchem.3c03941
PMID:	38315637
قاعدة البيانات:	MEDLINE

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الوصف
تدمد:	1520-510X
DOI:	10.1021/acs.inorgchem.3c03941