دورية أكاديمية

Microwave-induced combustion for further determination of potentially toxic elements in honey by ICP-MS.

التفاصيل البيبلوغرافية
العنوان: Microwave-induced combustion for further determination of potentially toxic elements in honey by ICP-MS.
المؤلفون: Cauduro VH; Departamento de Química, Universidade Federal de Santa Maria, Santa Maria, RS, 97105-900, Brazil., Alves CMAC; Departamento de Química, Universidade Federal de Santa Maria, Santa Maria, RS, 97105-900, Brazil., Nascimento MS; Departamento de Química, Universidade Federal de Santa Maria, Santa Maria, RS, 97105-900, Brazil., Druzian GT; Departamento de Química, Universidade Federal de Santa Maria, Santa Maria, RS, 97105-900, Brazil., Balbinot FP; Centro de Ciências Químicas, Farmacêuticas e de Alimentos, Universidade Federal de Pelotas, Capão do Leão, RS, 96160-000, Brazil., Mesko MF; Centro de Ciências Químicas, Farmacêuticas e de Alimentos, Universidade Federal de Pelotas, Capão do Leão, RS, 96160-000, Brazil., Flores EMM; Departamento de Química, Universidade Federal de Santa Maria, Santa Maria, RS, 97105-900, Brazil. ericommf@gmail.com.
المصدر: Analytical and bioanalytical chemistry [Anal Bioanal Chem] 2024 May; Vol. 416 (11), pp. 2859-2870. Date of Electronic Publication: 2024 Mar 09.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Springer-Verlag Country of Publication: Germany NLM ID: 101134327 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1618-2650 (Electronic) Linking ISSN: 16182642 NLM ISO Abbreviation: Anal Bioanal Chem Subsets: MEDLINE
أسماء مطبوعة: Original Publication: Heidelberg : Springer-Verlag, 2002-
مواضيع طبية MeSH: Microwaves* , Honey*, Mass Spectrometry/methods ; Lead ; Spectrum Analysis
مستخلص: Microwave-induced combustion (MIC) was proposed in this study for honey decomposition aiming for As, Cd, Hg, and Pb determination by inductively coupled plasma mass spectrometry (ICP-MS). Sample mass (up to 1.0 g), absorbing solution (0.5 to 14.4 mol L -1 HNO 3 , and H 2 O), heating program, and combustion aids were evaluated. The Eurachem guidelines were used for method validation. The proposed method enabled combustion of a high sample mass (0.8 g of honey, with 0.4 g of microcrystalline cellulose and 100 µL of 6 mol L -1 NH 4 NO 3 ) using 6 mL of an absorbing solution consisting of 1 mol L -1 HNO 3 , which resulted in low residual carbon in solution (< 25 mg L -1 ). Honey samples from different geographical origins were analyzed. Results showed no significant difference in comparison to other two microwave decomposition methods, based on microwave-assisted wet digestion with single reaction chamber (MAWD-SRC) and microwave-assisted wet digestion (MAWD). Standard addition experiments resulted in recoveries higher than 98%. The limits of detection ranged from 1.10 (As) to 4.60 ng g -1 (Pb). In addition to using only diluted reagents and resulting in digests virtually free of interferences, the proposed method was faster (< 30 min) than most of those presented in the literature.
(© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature.)
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معلومات مُعتمدة: 88887.137487/2017-00 Instituto Nacional de Ciência e Tecnologia de Bioanalítica; 312271/2017-4 Conselho Nacional de Desenvolvimento Científico e Tecnológico; 313786/2019-4 Conselho Nacional de Desenvolvimento Científico e Tecnológico; 409548/2021-9 Conselho Nacional de Desenvolvimento Científico e Tecnológico; finance code 001 Coordenação de Aperfeiçoamento de Pessoal de Nível Superior; 17/2551-0000960-6 Fundação de Amparo à Pesquisa do Estado do Rio Grande do Sul; 21/2551-0002091-1 Fundação de Amparo à Pesquisa do Estado do Rio Grande do Sul; 22/2551-0000389-3 Fundação de Amparo à Pesquisa do Estado do Rio Grande do Sul
فهرسة مساهمة: Keywords: Honey analysis; ICP-MS; Inorganic contaminants in honey; Microwave-induced combustion; Sample preparation; Toxic element determination
المشرفين على المادة: 2P299V784P (Lead)
تواريخ الأحداث: Date Created: 20240309 Date Completed: 20240415 Latest Revision: 20240729
رمز التحديث: 20240729
DOI: 10.1007/s00216-024-05235-7
PMID: 38459967
قاعدة البيانات: MEDLINE
الوصف
تدمد:1618-2650
DOI:10.1007/s00216-024-05235-7