دورية أكاديمية

Pyrite-assisted degradation of methoxychlor by laccase immobilized on Fe 3 S 4 /earthworm-like mesoporous SiO 2 .

التفاصيل البيبلوغرافية
العنوان: Pyrite-assisted degradation of methoxychlor by laccase immobilized on Fe 3 S 4 /earthworm-like mesoporous SiO 2 .
المؤلفون: Yang J; School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai, 200237, China., Yang Y; School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai, 200237, China. yxyang@ecust.edu.cn., Chang Z; School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai, 200237, China., Huang Y; School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai, 200237, China., Yuan H; State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130012, China., Zhao Y; School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai, 200237, China., Liu X; Analysis Test Center, Yangzhou University, Yangzhou, 225009, People's Republic of China., Ni C; Department of Materials Science and Engineering, University of Delaware, Newark, DE, 19716, USA.
المصدر: Environmental science and pollution research international [Environ Sci Pollut Res Int] 2024 Apr; Vol. 31 (17), pp. 25202-25215. Date of Electronic Publication: 2024 Mar 11.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Springer Country of Publication: Germany NLM ID: 9441769 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1614-7499 (Electronic) Linking ISSN: 09441344 NLM ISO Abbreviation: Environ Sci Pollut Res Int Subsets: MEDLINE
أسماء مطبوعة: Publication: <2013->: Berlin : Springer
Original Publication: Landsberg, Germany : Ecomed
مواضيع طبية MeSH: Methoxychlor*/chemistry , Oligochaeta*/metabolism , Iron*, Animals ; Enzymes, Immobilized/chemistry ; Laccase/metabolism ; Silicon Dioxide/chemistry ; Sulfides
مستخلص: Laccase immobilized and cross-linked on Fe 3 S 4 /earthworm-like mesoporous SiO 2 (Fe 3 S 4 /EW-mSiO 2 ) was used to degrade methoxychlor (MXC) in aqueous environments. The effects of various parameters on the degradation of MXC were determined using free and immobilized laccase. Immobilization improved the thermal stability and reuse of laccase significantly. Under the conditions of pH 4.5, temperature 40 °C, and reaction time 8 h, the degradation rate of MXC by immobilized laccase reached a maximum value of 40.99% and remained at 1/3 of the original after six cycles. The excellent degradation performance of Fe 3 S 4 /EW-mSiO 2 was attributable to the pyrite (FeS 2 ) impurity in Fe 3 S 4 , which could act as an electron donor in reductive dehalogenation. Sulfide groups and Fe 2+ reduced the activation energy of the system resulting in pyrite-assisted degradation of MXC. The degradation mechanism of MXC in aqueous environments by laccase immobilized on Fe 3 S 4 /EW-mSiO 2 was determined via mass spectroscopy of the degradation products. This study is a new attempt to use pyrite to support immobilized laccase degradation.
(© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)
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معلومات مُعتمدة: 20577010 National Natural Science Foundation of China; 20971043 National Natural Science Foundation of China
فهرسة مساهمة: Keywords: Fe3S4/earthworm-like mesoporous SiO2; Immobilized laccase; Methoxychlor
المشرفين على المادة: RIA79UD69L (Methoxychlor)
0 (Enzymes, Immobilized)
132N09W4PR (pyrite)
EC 1.10.3.2 (Laccase)
7631-86-9 (Silicon Dioxide)
0 (greigite)
0 (Sulfides)
E1UOL152H7 (Iron)
تواريخ الأحداث: Date Created: 20240311 Date Completed: 20240419 Latest Revision: 20240419
رمز التحديث: 20240419
DOI: 10.1007/s11356-024-32420-z
PMID: 38466381
قاعدة البيانات: MEDLINE
الوصف
تدمد:1614-7499
DOI:10.1007/s11356-024-32420-z