دورية أكاديمية
Mercury-Group 13 Metal Covalent Bonds: A Systematic Comparison of Aluminyl, Gallyl and Indyl Metallo-ligands.
| العنوان: | Mercury-Group 13 Metal Covalent Bonds: A Systematic Comparison of Aluminyl, Gallyl and Indyl Metallo-ligands. |
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| المؤلفون: | Griffin LP; Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK., Ellwanger MA; Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK., Crumpton AE; Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK., Roy MMD; Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK., Heilmann A; Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK., Aldridge S; Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK. |
| المصدر: | Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2024 Jun 03; Vol. 63 (23), pp. e202404527. Date of Electronic Publication: 2024 Apr 22. |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 0370543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-3773 (Electronic) Linking ISSN: 14337851 NLM ISO Abbreviation: Angew Chem Int Ed Engl Subsets: PubMed not MEDLINE; MEDLINE |
| أسماء مطبوعة: | Publication: <2004-> : Weinheim : Wiley-VCH Original Publication: Weinheim/Bergstr. : New York, : Verlag Chemie ; Academic Press, c1962- |
| مستخلص: | Bimetallic compounds containing direct metal-group 13 element bonds have been shown to display unprecedented patterns of cooperative reactivity towards small molecules, which can be influenced by the identity of the group 13 element. In this context, we present here a systematic appraisal of group 13 metallo-ligands of the type [(NON)E] - (NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene) for E=Al, Ga and In, through a comparison of structural and spectroscopic parameters associated with the trans L or X ligands in linear d 10 complexes of the types LM{E(NON)} and XM'{E(NON)}. These studies are facilitated by convenient syntheses (from the In(I) precursor, InCp) of the potassium indyl species [{K(NON)In}⋅KCp] (© 2024 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.) |
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| معلومات مُعتمدة: | EP/S023828/1 Engineering and Physical Sciences Research Council; Leverhulme Trust; Alexander von Humboldt-Stiftung |
| فهرسة مساهمة: | Keywords: aluminyl; gallyl; group 13 elements; indyl; low valent compounds; mercury |
| تواريخ الأحداث: | Date Created: 20240328 Latest Revision: 20240524 |
| رمز التحديث: | 20240524 |
| DOI: | 10.1002/anie.202404527 |
| PMID: | 38545953 |
| قاعدة البيانات: | MEDLINE |
Full Text Finder | تدمد: | 1521-3773 |
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| DOI: | 10.1002/anie.202404527 |