دورية أكاديمية
أعرض في EDS

Reprocessability in Engineering Thermosets Achieved Through Frontal Ring-Opening Metathesis Polymerization.

التفاصيل البيبلوغرافية
العنوان: Reprocessability in Engineering Thermosets Achieved Through Frontal Ring-Opening Metathesis Polymerization.
المؤلفون: Cooper JC; Beckman Institute for Advanced Science and Technology, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA.; Department of Chemistry, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA., Paul JE; Beckman Institute for Advanced Science and Technology, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA.; Department of Materials Science and Engineering, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA., Ramlawi N; Department of Mechanical Science and Engineering, University of Illinois Urban-Champaign, Urbana, IL, 61801, USA., Saengow C; Beckman Institute for Advanced Science and Technology, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA.; Department of Mechanical Science and Engineering, University of Illinois Urban-Champaign, Urbana, IL, 61801, USA., Sharma A; Beckman Institute for Advanced Science and Technology, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA.; Department of Materials Science and Engineering, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA., Suslick BA; Beckman Institute for Advanced Science and Technology, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA.; Department of Chemistry, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA., Ewoldt RH; Beckman Institute for Advanced Science and Technology, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA.; Department of Mechanical Science and Engineering, University of Illinois Urban-Champaign, Urbana, IL, 61801, USA., Sottos NR; Beckman Institute for Advanced Science and Technology, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA.; Department of Materials Science and Engineering, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA., Moore JS; Beckman Institute for Advanced Science and Technology, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA.; Department of Chemistry, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA.
المصدر: Advanced materials (Deerfield Beach, Fla.) [Adv Mater] 2024 Jul; Vol. 36 (28), pp. e2402627. Date of Electronic Publication: 2024 May 03.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 9885358 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-4095 (Electronic) Linking ISSN: 09359648 NLM ISO Abbreviation: Adv Mater Subsets: PubMed not MEDLINE; MEDLINE
أسماء مطبوعة: Publication: Sept. 3, 1997- : Weinheim : Wiley-VCH
Original Publication: Deerfield Beach, FL : VCH Publishers, 1989-
مستخلص: While valued for their durability and exceptional performance, crosslinked thermosets are challenging to recycle and reuse. Here, inherent reprocessability in industrially relevant polyolefin thermosets is unveiled. Unlike prior methods, this approach eliminates the need to introduce exchangeable functionality to regenerate the material, relying instead on preserving the activity of the metathesis catalyst employed in the curing reaction. Frontal ring-opening metathesis polymerization (FROMP) proves critical to preserving this activity. Conditions controlling catalytic viability are explored to successfully reclaim performance across multiple generations of material, thus demonstrating long-term reprocessability. This straightforward and scalable remolding strategy is poised for widespread adoption. Given the anticipated growth in polyolefin thermosets, these findings represent an important conceptual advance in the pursuit of a fully circular lifecycle for thermoset polymers.
(© 2024 The Authors. Advanced Materials published by Wiley‐VCH GmbH.)
References: J.‐P. Pascault, H. Sautereau, J. Verdu, R. J. J. Williams, Thermosetting Polymers, CRC Press, New York, 2002.
W. Post, A. Susa, R. Blaauw, K. Molenveld, R. J. I. Knoop, Polym. Rev. 2020, 60, 359.
M. Rani, P. Choudhary, V. Krishnan, S. Zafar, Composites, Part B 2021, 215, 108768.
C. J. Kloxin, T. F. Scott, B. J. Adzima, C. N. Bowman, Macromolecules 2010, 43, 2643.
B. R. Elling, W. R. Dichtel, ACS Cent. Sci. 2020, 6, 1488.
D. J. Fortman, J. P. Brutman, G. X. De Hoe, R. L. Snyder, W. R. Dichtel, M. A. Hillmyer, ACS Sustainable Chem. Eng. 2018, 6, 11145.
G. M. Scheutz, J. J. Lessard, M. B. Sims, B. S. Sumerlin, J. Am. Chem. Soc. 2019, 141, 16181.
F. Caffy, R. Nicolaÿ, Polym. Chem. 2019, 10, 3107.
M. Röttger, T. Domenech, R. van der Weegen, A. Breuillac, R. Nicolaÿ, L. Leibler, Science 2017, 356, 62.
J. J. Lessard, K. A. Stewart, B. S. Sumerlin, Macromolecules 2022, 55, 10052.
J. S. A. Ishibashi, J. A. Kalow, ACS Macro Lett. 2018, 7, 482.
W. Denissen, G. Rivero, R. Nicolaÿ, L. Leibler, J. M. Winne, F. E. Du Prez, Adv. Funct. Mater. 2015, 25, 2451.
J. J. Lessard, G. M. Scheutz, R. W. Hughes, B. S. Sumerlin, ACS Appl. Polym. Mater. 2020, 2, 3044.
K. E. L. Husted, C. M. Brown, P. Shieh, I. Kevlishvili, S. L. Kristufek, H. Zafar, J. V. Accardo, J. C. Cooper, R. S. Klausen, H. J. Kulik, J. S. Moore, N. R. Sottos, J. A. Kalow, J. A. Johnson, J. Am. Chem. Soc. 2023, 145, 1916.
D. J. Fortman, J. P. Brutman, C. J. Cramer, M. A. Hillmyer, W. R. Dichtel, J. Am. Chem. Soc. 2015, 137, 14019.
D. Montarnal, M. Capelot, F. Tournilhac, L. Leibler, Science 2011, 334, 965.
J. L. Self, N. D. Dolinski, M. S. Zayas, J. Read de Alaniz, C. M. Bates, ACS Macro Lett. 2018, 7, 817.
D. G. Ivanoff, J. Sung, S. M. Butikofer, J. S. Moore, N. R. Sottos, Macromolecules 2020, 53, 8360.
J. Chen, F. P. Burns, M. G. Moffitt, J. E. Wulff, ACS Omega 2016, 1, 532.
L. M. Dean, Q. Wu, O. Alshangiti, J. S. Moore, N. R. Sottos, ACS Macro Lett. 2020, 9, 819.
K. E. L. Husted, P. Shieh, D. J. Lundberg, S. L. Kristufek, J. A. Johnson, ACS Macro Lett. 2021, 10, 805.
E. M. Lloyd, J. C. Cooper, P. Shieh, D. G. Ivanoff, N. A. Parikh, E. B. Mejia, K. E. L. Husted, L. C. Costa, N. R. Sottos, J. A. Johnson, J. S. Moore, ACS Appl. Eng. Mater. 2023, 1, 477.
Y.‐X. Lu, F. Tournilhac, L. Leibler, Z. Guan, J. Am. Chem. Soc. 2012, 134, 8424.
Y. X. Lu, Z. Guan, J. Am. Chem. Soc. 2012, 134, 14226.
H. Liu, A. Z. Nelson, Y. Ren, K. Yang, R. H. Ewoldt, J. S. Moore, ACS Macro Lett. 2018, 7, 933.
J. A. Neal, D. Mozhdehi, Z. Guan, J. Am. Chem. Soc. 2015, 137, 4846.
M. Bell, H. G. Hester, A. N. Gallman, V. Gomez, J. Pribyl, G. Rojas, A. Riegger, T. Weil, H. Watanabe, Y. Chujo, K. B. Wagener, Macromol. Chem. Phys. 2019, 220, 1900223.
D. M. Alzate‐Sanchez, C. H. Yu, J. J. Lessard, J. E. Paul, N. R. Sottos, J. S. Moore, Macromolecules 2023, 56, 1527.
A. Mariani, S. Fiori, Y. Chekanov, J. A. Pojman, Macromolecules 2001, 34, 6539.
B. A. Suslick, J. Hemmer, B. R. Groce, K. J. Stawiasz, P. H. Geubelle, G. Malucelli, A. Mariani, J. S. Moore, J. A. Pojman, N. R. Sottos, Chem. Rev. 2023, 123, 3237.
I. D. Robertson, M. Yourdkhani, P. J. Centellas, J. E. Aw, D. G. Ivanoff, E. Goli, E. M. Lloyd, L. M. Dean, N. R. Sottos, P. H. Geubelle, J. S. Moore, S. R. White, Nature 2018, 557, 223.
B. A. Suslick, K. J. Stawiasz, J. E. Paul, N. R. Sottos, J. S. Moore, Macromolecules 2021, 54, 5117.
S. Wolf, H. Plenio, Green Chem. 2011, 13, 2008.
J. Huang, H. J. Schanz, E. D. Stevens, S. P. Nolan, Organometallics 1999, 18, 5375.
J. Huang, E. D. Stevens, S. P. Nolan, J. L. Petersen, J. Am. Chem. Soc. 1999, 121, 2674.
W. A. Yehye, N. A. Rahman, A. Ariffin, S. B. Abd Hamid, A. A. Alhadi, F. A. Kadir, M. Yaeghoobi, Eur. J. Med. Chem. 2015, 101, 295.
M. L. Martins, X. Zhao, Z. Demchuk, J. Luo, G. P. Carden, G. Toleutay, A. P. Sokolov, Macromolecules 2023, 56, 8688.
P. Shieh, W. Zhang, K. E. L. Husted, S. L. Kristufek, B. Xiong, D. J. Lundberg, J. Lem, D. Veysset, Y. Sun, K. A. Nelson, D. L. Plata, J. A. Johnson, Nature 2020, 583, 542.
D. R. Kelsey, D. L. Handlin Jr., M. Narayana, B. M. Scardino, J. Polym. Sci., Part A: Polym. Chem. 1997, 35, 3027.
H. G. Kim, H. J. Son, D. K. Lee, D. W. Kim, H. J. Park, D. H. Cho, Korean J. Chem. Eng. 2017, 34, 2099.
C. J. Cruce, M. S. Trimmer, J. L. Moore, WO2016130743A1, 2019.
B. J. Rohde, K. M. Le, R. Krishnamoorti, M. L. Robertson, Macromolecules 2016, 49, 8960.
M. Jawiczuk, A. Marczyk, B. Trzaskowski, Catalysts 2020, 10, 887.
G. A. Bailey, M. Foscato, C. S. Higman, C. S. Day, V. R. Jensen, D. E. Fogg, J. Am. Chem. Soc. 2018, 140, 6931.
S. H. Hong, A. G. Wenzel, T. T. Salguero, M. W. Day, R. H. Grubbs, J. Am. Chem. Soc. 2007, 129, 7961.
D. Bourgeois, A. Pancrazi, S. P. Nolan, J. Prunet, J. Organomet. Chem. 2002, 643–644, 247.
W. Janse Van Rensburg, P. J. Steynberg, W. H. Meyer, M. M. Kirk, G. S. Forman, J. Am. Chem. Soc. 2004, 126, 14332.
J. Engel, W. Smit, M. Foscato, G. Occhipinti, K. W. Törnroos, V. R. Jensen, J. Am. Chem. Soc. 2017, 139, 16609.
F. C. Courchay, J. C. Sworen, I. Ghiviriga, K. A. Abboud, K. B. Wagener, Organometallics 2006, 25, 6074.
S. H. Hong, M. W. Day, R. H. Grubbs, J. Am. Chem. Soc. 2004, 126, 7414.
W. Kauzmann, H. Eyring, J. Am. Chem. Soc. 1940, 62, 3113.
P. C. Hiemenz, T. P. Lodge, Polymer Chemistry, CRC Press, Boca Raton, FL, USA 2007.
J. Bidange, C. Fischmeister, C. Bruneau, Chem. Eur. J. 2016, 22, 12226.
معلومات مُعتمدة: FA9550-20-1-0194 Air Force Office of Scientific Research
فهرسة مساهمة: Keywords: engineering thermosets; frontal polymerization; multigenerational materials; reprocessability; thermoset sustainability
تواريخ الأحداث: Date Created: 20240423 Latest Revision: 20240711
رمز التحديث: 20240712
DOI: 10.1002/adma.202402627
PMID: 38652482
قاعدة البيانات: MEDLINE
الوصف
تدمد:1521-4095
DOI:10.1002/adma.202402627