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An isolable, chelating bis[cyclic (alkyl)(amino)carbene] stabilizes a strongly bent, dicoordinate Ni(0) complex.

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العنوان: An isolable, chelating bis[cyclic (alkyl)(amino)carbene] stabilizes a strongly bent, dicoordinate Ni(0) complex.
المؤلفون: Puerta Lombardi BM; Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, Canada., Faas MR; Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, Canada., West D; Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, Canada., Suvinen RA; Department of Chemistry, NanoScience Centre, University of Jyvӓskylӓ, Jyvӓskylӓ, Finland., Tuononen HM; Department of Chemistry, NanoScience Centre, University of Jyvӓskylӓ, Jyvӓskylӓ, Finland. heikki.m.tuononen@jyu.fi., Roesler R; Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, Canada. roesler@ucalgary.ca.
المصدر: Nature communications [Nat Commun] 2024 Apr 23; Vol. 15 (1), pp. 3417. Date of Electronic Publication: 2024 Apr 23.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Nature Pub. Group Country of Publication: England NLM ID: 101528555 Publication Model: Electronic Cited Medium: Internet ISSN: 2041-1723 (Electronic) Linking ISSN: 20411723 NLM ISO Abbreviation: Nat Commun Subsets: PubMed not MEDLINE; MEDLINE
أسماء مطبوعة: Original Publication: [London] : Nature Pub. Group
مستخلص: Chelating ligands have had a tremendous impact in coordination chemistry and catalysis. Notwithstanding their success as strongly σ-donating and π-accepting ligands, to date no chelating bis[cyclic (alkyl)(amino)carbenes] have been reported. Herein, we describe a chelating, C 2 -symmetric bis[cyclic (alkyl)(amino)carbene] ligand, which was isolated as a racemic mixture. The isolation and structural characterization of its isostructural, pseudotetrahedral complexes with iron, cobalt, nickel, and zinc dihalides featuring eight-membered metallacycles demonstrates the binding ability of the bis(carbene). Reduction of the nickel(II) dibromide with potassium graphite produces a dicoordinate nickel(0) complex that features one of the narrowest angles measured in any unsupported dicoordinate transition metal complexes.
(© 2024. The Author(s).)
References: Chem Commun (Camb). 2022 Sep 15;58(74):10396-10399. (PMID: 36039867)
ACS Catal. 2023 Jun 16;13(12):7966-7977. (PMID: 38037565)
Angew Chem Int Ed Engl. 2015 Jan 7;54(2):532-5. (PMID: 25394570)
Chem Asian J. 2022 Apr 1;17(7):e202101301. (PMID: 34989475)
Chem Rev. 2020 Jul 8;120(13):6124-6196. (PMID: 32491839)
J Am Chem Soc. 2018 Nov 14;140(45):15166-15169. (PMID: 30381949)
J Am Chem Soc. 2020 Mar 11;142(10):4560-4564. (PMID: 32088963)
Angew Chem Int Ed Engl. 2019 Jan 2;58(1):154-158. (PMID: 30408328)
Acc Chem Res. 2015 Feb 17;48(2):256-66. (PMID: 25515548)
Inorg Chem. 2005 May 30;44(11):3774-6. (PMID: 15907100)
Angew Chem Int Ed Engl. 2005 Sep 5;44(35):5705-9. (PMID: 16059961)
J Org Chem. 1997 Nov 14;62(23):8024-8030. (PMID: 11671907)
J Am Chem Soc. 2014 Aug 27;136(34):11964-71. (PMID: 25072104)
Angew Chem Int Ed Engl. 2017 Aug 14;56(34):10046-10068. (PMID: 28376253)
Chemistry. 2014 Sep 8;20(37):11646-9. (PMID: 25047010)
Proc Natl Acad Sci U S A. 2007 Aug 21;104(34):13569-73. (PMID: 17698808)
J Am Chem Soc. 2016 Jun 29;138(25):7884-7. (PMID: 27304485)
Nat Commun. 2020 Jan 21;11(1):417. (PMID: 31964876)
J Am Chem Soc. 2019 Feb 6;141(5):1908-1912. (PMID: 30633503)
Proc Natl Acad Sci U S A. 2004 Apr 20;101(16):5723-6. (PMID: 15069193)
J Am Chem Soc. 2017 Jun 14;139(23):7753-7756. (PMID: 28541687)
Chem Commun (Camb). 2022 Jun 1;58(45):6482-6485. (PMID: 35583166)
Proc Natl Acad Sci U S A. 2004 Apr 13;101(15):5348-55. (PMID: 14990801)
Dalton Trans. 2008 May 7;(17):2238-40. (PMID: 18414746)
Acta Crystallogr A Found Adv. 2015 Jan;71(Pt 1):3-8. (PMID: 25537383)
J Am Chem Soc. 2003 Jul 2;125(26):7816-7. (PMID: 12822996)
Chemistry. 2001 Apr 17;7(8):1614-8. (PMID: 11349901)
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2016 Apr;72(Pt 2):171-9. (PMID: 27048719)
Science. 2017 Sep 1;357(6354):908-912. (PMID: 28798044)
Dalton Trans. 2008 Jan 7;(1):30-1. (PMID: 18399222)
Acc Chem Res. 2020 Apr 21;53(4):906-919. (PMID: 32237734)
J Am Chem Soc. 2019 Apr 3;141(13):5164-5168. (PMID: 30896933)
Acta Crystallogr C Struct Chem. 2015 Jan;71(Pt 1):3-8. (PMID: 25567568)
Angew Chem Int Ed Engl. 2020 May 11;59(20):7906-7914. (PMID: 32129920)
Chem Rev. 2009 Aug;109(8):3677-707. (PMID: 19236010)
Chem Rev. 2012 Jun 13;112(6):3482-507. (PMID: 22480221)
ChemistryOpen. 2013 Jun;2(3):106-14. (PMID: 24551547)
J Am Chem Soc. 2018 Jul 25;140(29):9255-9260. (PMID: 29954178)
Nat Chem. 2016 Jul;8(7):638-42. (PMID: 27334631)
Chem Sci. 2015 Feb 1;6(2):1426-1432. (PMID: 29560231)
J Am Chem Soc. 2018 Feb 14;140(6):2206-2213. (PMID: 29342351)
Chemistry. 2022 Oct 21;28(59):e202202237. (PMID: 35899619)
Acc Chem Res. 2016 Mar 15;49(3):357-69. (PMID: 26925983)
J Am Chem Soc. 2018 Feb 21;140(7):2546-2554. (PMID: 29382199)
Chem Rev. 2018 Oct 10;118(19):9678-9842. (PMID: 29969239)
Chem Sci. 2017 Dec 13;9(5):1155-1167. (PMID: 29675160)
Chem Commun (Camb). 2022 Jul 5;58(54):7519-7521. (PMID: 35699417)
معلومات مُعتمدة: 2019-07195 Gouvernement du Canada | Natural Sciences and Engineering Research Council of Canada (Conseil de Recherches en Sciences Naturelles et en Génie du Canada); 2019-07195 Gouvernement du Canada | Natural Sciences and Engineering Research Council of Canada (Conseil de Recherches en Sciences Naturelles et en Génie du Canada); 2019-07195 Gouvernement du Canada | Natural Sciences and Engineering Research Council of Canada (Conseil de Recherches en Sciences Naturelles et en Génie du Canada); 2019-07195 Gouvernement du Canada | Natural Sciences and Engineering Research Council of Canada (Conseil de Recherches en Sciences Naturelles et en Génie du Canada); 772510 EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council); 772510 EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council); 772510 EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council)
تواريخ الأحداث: Date Created: 20240423 Latest Revision: 20240426
رمز التحديث: 20240426
مُعرف محوري في PubMed: PMC11039645
DOI: 10.1038/s41467-024-47036-7
PMID: 38653986
قاعدة البيانات: MEDLINE
الوصف
تدمد:2041-1723
DOI:10.1038/s41467-024-47036-7