دورية أكاديمية
Intra- and Intermolecular Charge-Transfer Dynamics of Carbene-Metal-Amide Photosensitizers.
العنوان: | Intra- and Intermolecular Charge-Transfer Dynamics of Carbene-Metal-Amide Photosensitizers. |
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المؤلفون: | Kellogg MS; Department of Chemistry, University of Southern California, Los Angeles, California 90089, United States., Mencke AR; Department of Chemistry, University of Southern California, Los Angeles, California 90089, United States., Muniz CN; Department of Chemistry, University of Southern California, Los Angeles, California 90089, United States., Nattikallungal TA; Department of Chemistry, University of Southern California, Los Angeles, California 90089, United States., Cardoso-Delgado F; Department of Chemistry, University of Southern California, Los Angeles, California 90089, United States., Baluyot-Reyes N; Department of Chemistry, University of Southern California, Los Angeles, California 90089, United States., Sewell M; Department of Chemistry, University of California, Riverside, California 92521, United States., Bird MJ; Chemistry Division, Brookhaven National Laboratory, Upton, New York 11973, United States., Bradforth SE; Department of Chemistry, University of Southern California, Los Angeles, California 90089, United States., Thompson ME; Department of Chemistry, University of Southern California, Los Angeles, California 90089, United States. |
المصدر: | The journal of physical chemistry. C, Nanomaterials and interfaces [J Phys Chem C Nanomater Interfaces] 2024 Apr 12; Vol. 128 (16), pp. 6621-6635. Date of Electronic Publication: 2024 Apr 12 (Print Publication: 2024). |
نوع المنشور: | Journal Article |
اللغة: | English |
بيانات الدورية: | Publisher: American Chemical Society Country of Publication: United States NLM ID: 101299949 Publication Model: eCollection Cited Medium: Print ISSN: 1932-7447 (Print) Linking ISSN: 19327447 NLM ISO Abbreviation: J Phys Chem C Nanomater Interfaces Subsets: PubMed not MEDLINE |
أسماء مطبوعة: | Original Publication: Washington DC : American Chemical Society, c2007- |
مستخلص: | A series of steady-state and time-resolved spectroscopies were performed on a set of eight carbene-metal-amide (cMa) complexes, where M = Cu and Au, that have been used as photosensitizers for photosensitized electrocatalytic reactions. Using ps-to-ns and ns-to-ms transient absorption spectroscopies (psTA and nsTA, respectively), the excited-state kinetics from light absorption, intersystem crossing (ISC), and eventually intermolecular charge transfer were thoroughly characterized. Using time-correlated single photon counting (TCSPC) and psTA with a thermally activated delayed fluorescence (TADF) model, the variation in intersystem crossing (ISC), ( S Competing Interests: The authors declare no competing financial interest. (© 2024 The Authors. Published by American Chemical Society.) |
التعليقات: | Erratum in: J Phys Chem C Nanomater Interfaces. 2024 Jun 10;128(24):10246-10247. doi: 10.1021/acs.jpcc.4c03368. (PMID: 38919727) |
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تواريخ الأحداث: | Date Created: 20240501 Latest Revision: 20240626 |
رمز التحديث: | 20240626 |
مُعرف محوري في PubMed: | PMC11056983 |
DOI: | 10.1021/acs.jpcc.4c01994 |
PMID: | 38690534 |
قاعدة البيانات: | MEDLINE |
تدمد: | 1932-7447 |
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DOI: | 10.1021/acs.jpcc.4c01994 |