دورية أكاديمية

A Gold(I)-Acetylene Complex Synthesised using Single-Crystal Reactivity.

التفاصيل البيبلوغرافية
العنوان: A Gold(I)-Acetylene Complex Synthesised using Single-Crystal Reactivity.
المؤلفون: Johnson CL; Department of Chemistry, University of York, York, YO10 5DD, UK., Storm DJ; EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, KY16 9ST, UK., Sajjad MA; EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, KY16 9ST, UK., Gyton MR; Department of Chemistry, University of York, York, YO10 5DD, UK., Duckett SB; Department of Chemistry, University of York, York, YO10 5DD, UK., Macgregor SA; EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, KY16 9ST, UK., Weller AS; Department of Chemistry, University of York, York, YO10 5DD, UK., Navarro M; Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Consejo Superior de Investigaciones Científicas (CSIC) and University of Sevilla, 41092, Sevilla, Spain., Campos J; Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Consejo Superior de Investigaciones Científicas (CSIC) and University of Sevilla, 41092, Sevilla, Spain.
المصدر: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2024 Jul 22; Vol. 63 (30), pp. e202404264. Date of Electronic Publication: 2024 Jun 20.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 0370543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-3773 (Electronic) Linking ISSN: 14337851 NLM ISO Abbreviation: Angew Chem Int Ed Engl Subsets: PubMed not MEDLINE; MEDLINE
أسماء مطبوعة: Publication: <2004-> : Weinheim : Wiley-VCH
Original Publication: Weinheim/Bergstr. : New York, : Verlag Chemie ; Academic Press, c1962-
مستخلص: Using single-crystal to single-crystal solid/gas reactivity the gold(I) acetylene complex [Au(L1)(η 2 -HC≡CH)][BAr F 4 ] is cleanly synthesized by addition of acetylene gas to single crystals of [Au(L1)(CO)][BAr F 4 ] [L1=tris-2-(4,4'-di-tert-butylbiphenyl)phosphine, Ar F =3,5-(CF 3 ) 2 C 6 H 3 ]. This simplest gold-alkyne complex has been characterized by single crystal X-ray diffraction, solution and solid-state NMR spectroscopy and periodic DFT. Bonding of HC≡CH with [Au(L1)] + comprises both σ-donation and π-backdonation with additional dispersion interactions within the cavity-shaped phosphine.
(© 2024 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)
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معلومات مُعتمدة: 756575 H2020 European Research Council; PID2022-139782NB-I00 Ministerio de Ciencia e Innovación; FJC2018-035514-I Ministerio de Ciencia e Innovación; DOC_00149 Agencia de Innovación y Desarrollo de Andalucía; RPG-2020-184 Leverhulme Trust; Wild Overseas Scholar's Fund; EP/W015498/1 Engineering and Physical Sciences Research Council; EP/ R026815/1 Engineering and Physical Sciences Research Council
فهرسة مساهمة: Keywords: X-ray diffraction; acetylene; bulky phosphine; gold(I); ligand cavity; single crystals; solid-state organometallic
تواريخ الأحداث: Date Created: 20240503 Latest Revision: 20240720
رمز التحديث: 20240721
DOI: 10.1002/anie.202404264
PMID: 38699962
قاعدة البيانات: MEDLINE
الوصف
تدمد:1521-3773
DOI:10.1002/anie.202404264