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Synthesis and Physical Properties of the Misfit Layered Compound (EuS) 1.13 (NbSe 2 ) 2 .

التفاصيل البيبلوغرافية
العنوان: Synthesis and Physical Properties of the Misfit Layered Compound (EuS) 1.13 (NbSe 2 ) 2 .
المؤلفون: Ng N; Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21218, United States., Foley DL; Department of Materials Science and Engineering, The Johns Hopkins University, Baltimore, Maryland 21218, United States., Zhang X; Department of Chemical and Biomolecular Engineering, The Johns Hopkins University, Baltimore, Maryland 21218, United States.; Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States., Redemann BWY; Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21218, United States., Taheri ML; Department of Materials Science and Engineering, The Johns Hopkins University, Baltimore, Maryland 21218, United States., McQueen TM; Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21218, United States.; Department of Materials Science and Engineering, The Johns Hopkins University, Baltimore, Maryland 21218, United States.; William H. Miller III Department of Physics and Astronomy, The Johns Hopkins University, Baltimore, Maryland 21218, United States.
المصدر: Inorganic chemistry [Inorg Chem] 2024 May 27; Vol. 63 (21), pp. 9726-9734. Date of Electronic Publication: 2024 May 14.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: American Chemical Society Country of Publication: United States NLM ID: 0366543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-510X (Electronic) Linking ISSN: 00201669 NLM ISO Abbreviation: Inorg Chem Subsets: PubMed not MEDLINE; MEDLINE
أسماء مطبوعة: Original Publication: [Easton, Pa.] American Chemical Society.
مستخلص: A new misfit layered compound with the stoichiometry (EuS) 1+δ (NbSe 2 ) 2 (δ ≈ 0.13) has been successfully synthesized. High-resolution transmission electron microscopy and powder X-ray diffraction confirm the misfit structure with (EuS)-(EuS) spacing of 18.30(1) Å. Magnetization, electrical resistivity, heat capacity, and thermal transport measurements show that the material is a heavily doped semiconductor or poor metal with a low thermal conductivity of ∼1 W/m K and an antiferromagnetic ordering transition at T N = 4.7 K. In contrast to the parent materials, the misfit is neither ferromagnetic nor superconducting down to T = 0.4 K. We find evidence of a field-driven transition to a ferromagnetic state due to reorientation of ferromagnetic EuS layers at μ o H = 0.5 T at T = 2 K.
تواريخ الأحداث: Date Created: 20240514 Latest Revision: 20240527
رمز التحديث: 20240527
DOI: 10.1021/acs.inorgchem.3c04289
PMID: 38743495
قاعدة البيانات: MEDLINE
الوصف
تدمد:1520-510X
DOI:10.1021/acs.inorgchem.3c04289