Chemoselective and Stereoselective Allylation of Bis(alkenyl)boronates.

التفاصيل البيبلوغرافية
العنوان:	Chemoselective and Stereoselective Allylation of Bis(alkenyl)boronates.
المؤلفون:	Tran MK; Department of Biochemistry, Division of Chemistry, UT Southwestern Medical Center, 5323 Harry Hines Blvd., Dallas, TX 75390-0938, USA., Ready JM; Department of Biochemistry, Division of Chemistry, UT Southwestern Medical Center, 5323 Harry Hines Blvd., Dallas, TX 75390-0938, USA.
المصدر:	Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2024 May 23, pp. e202407824. Date of Electronic Publication: 2024 May 23.
Publication Model:	Ahead of Print
نوع المنشور:	Journal Article
اللغة:	English
بيانات الدورية:	Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 0370543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-3773 (Electronic) Linking ISSN: 14337851 NLM ISO Abbreviation: Angew Chem Int Ed Engl Subsets: MEDLINE
أسماء مطبوعة:	Publication: <2004-> : Weinheim : Wiley-VCH Original Publication: Weinheim/Bergstr. : New York, : Verlag Chemie ; Academic Press, c1962-
مستخلص:	Bis(alkenyl)boronates react with optically active Ir(π-allyl) species in a process that involves allylation of the more substituted olefin and 1,2-metalate shift of the less substituted olefin. The method constructs valuable enantioenriched tertiary allylic boronic esters with high chemoselectivity, enantioselectivity and diastereoselectivity. Allylic functionalization reactions transform the 1,3-stereodiad to 1,5- and 1,6-stereochemical relationships. (© 2024 Wiley-VCH GmbH.)
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معلومات مُعتمدة:	I-1612 Welch Foundation
فهرسة مساهمة:	Keywords: Iridium; alkenyl boronate; allyl boronate; allylation; asymmetric catalysis
تواريخ الأحداث:	Date Created: 20240523 Latest Revision: 20240725
رمز التحديث:	20240726
DOI:	10.1002/anie.202407824
PMID:	38781007
قاعدة البيانات:	MEDLINE

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تدمد:	1521-3773
DOI:	10.1002/anie.202407824