دورية أكاديمية

Chemiresistors Based on Hybrid Nanostructures Obtained from Graphene and Conducting Polymers with Potential Use in Breath Methane Detection Associated with Irritable Bowel Syndrome.

التفاصيل البيبلوغرافية
العنوان: Chemiresistors Based on Hybrid Nanostructures Obtained from Graphene and Conducting Polymers with Potential Use in Breath Methane Detection Associated with Irritable Bowel Syndrome.
المؤلفون: Trandabat AF; Department of Electrical Measurements and Materials, Gheorghe Asachi Technical University, 700050 Iasi, Romania., Ciobanu RC; Department of Electrical Measurements and Materials, Gheorghe Asachi Technical University, 700050 Iasi, Romania., Schreiner OD; Department of Electrical Measurements and Materials, Gheorghe Asachi Technical University, 700050 Iasi, Romania., Schreiner TG; Department of Electrical Measurements and Materials, Gheorghe Asachi Technical University, 700050 Iasi, Romania.; Department of Medical Specialties III, Faculty of Medicine, University of Medicine and Pharmacy 'Grigore T. Popa', 700115 Iasi, Romania., Aradoaei S; Department of Electrical Measurements and Materials, Gheorghe Asachi Technical University, 700050 Iasi, Romania.
المصدر: International journal of molecular sciences [Int J Mol Sci] 2024 May 20; Vol. 25 (10). Date of Electronic Publication: 2024 May 20.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: MDPI Country of Publication: Switzerland NLM ID: 101092791 Publication Model: Electronic Cited Medium: Internet ISSN: 1422-0067 (Electronic) Linking ISSN: 14220067 NLM ISO Abbreviation: Int J Mol Sci Subsets: MEDLINE
أسماء مطبوعة: Original Publication: Basel, Switzerland : MDPI, [2000-
مواضيع طبية MeSH: Graphite*/chemistry , Nanostructures*/chemistry , Polymers*/chemistry , Methane*/chemistry , Irritable Bowel Syndrome*/metabolism, Humans ; Breath Tests/methods ; Thiophenes/chemistry ; Electric Conductivity
مستخلص: This paper describes the process of producing chemiresistors based on hybrid nanostructures obtained from graphene and conducting polymers. The technology of graphene presumed the following: dispersion and support stabilization based on the chemical vapor deposition technique; transfer of the graphene to the substrate by spin-coating of polymethyl methacrylate; and thermal treatment and electrochemical delamination. For the process at T = 950 °C, a better settlement of the grains was noticed, with the formation of layers predominantly characterized by peaks and not by depressions. The technology for obtaining hybrid nanostructures from graphene and conducting polymers was drop-casting, with solutions of Poly(3-hexylthiophene (P3HT) and Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-bithiophene] (F8T2). In the case of F8T2, compared to P3HT, a 10 times larger dimension of grain size and about 7 times larger distances between the peak clusters were noticed. To generate chemiresistors from graphene-polymer structures, an ink-jet printer was used, and the metallization was made with commercial copper ink for printed electronics, leading to a structure of a resistor with an active surface of about 1 cm 2 . Experimental calibration curves were plotted for both sensing structures, for a domain of CH 4 of up to 1000 ppm concentration in air. A linearity of the curve for the low concentration of CH 4 was noticed for the graphene structure with F8T2, presenting a sensitivity of about 6 times higher compared with the graphene structure with P3HT, which makes the sensing structure of graphene with F8T2 more feasible and reliable for the medical application of irritable bowel syndrome evaluation.
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فهرسة مساهمة: Keywords: breath methane detection; chemiresistor; conducting polymers; graphene; irritable bowel syndrome
المشرفين على المادة: 7782-42-5 (Graphite)
0 (Polymers)
OP0UW79H66 (Methane)
0 (Thiophenes)
تواريخ الأحداث: Date Created: 20240525 Date Completed: 20240525 Latest Revision: 20240527
رمز التحديث: 20240527
مُعرف محوري في PubMed: PMC11121982
DOI: 10.3390/ijms25105552
PMID: 38791590
قاعدة البيانات: MEDLINE
الوصف
تدمد:1422-0067
DOI:10.3390/ijms25105552