دورية أكاديمية
ZIF-8@Hydroxyapatite Composite as a High Potential Material for Prolonged Delivery of Agrochemicals.
العنوان: | ZIF-8@Hydroxyapatite Composite as a High Potential Material for Prolonged Delivery of Agrochemicals. |
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المؤلفون: | Morales-Cámara S; Department of Inorganic Chemistry, University of Granada, Av. Fuentenueva, s/n, 18071 Granada, Spain., Parra-Torrejón B; Department of Inorganic Chemistry, University of Granada, Av. Fuentenueva, s/n, 18071 Granada, Spain., Rodríguez-Diéguez A; Department of Inorganic Chemistry, University of Granada, Av. Fuentenueva, s/n, 18071 Granada, Spain., Delgado-López JM; Department of Inorganic Chemistry, University of Granada, Av. Fuentenueva, s/n, 18071 Granada, Spain., Ramírez-Rodríguez GB; Department of Inorganic Chemistry, University of Granada, Av. Fuentenueva, s/n, 18071 Granada, Spain., Rojas S; Department of Inorganic Chemistry, University of Granada, Av. Fuentenueva, s/n, 18071 Granada, Spain. |
المصدر: | ACS applied materials & interfaces [ACS Appl Mater Interfaces] 2024 Jun 05; Vol. 16 (22), pp. 29305-29313. Date of Electronic Publication: 2024 May 27. |
نوع المنشور: | Journal Article |
اللغة: | English |
بيانات الدورية: | Publisher: American Chemical Society Country of Publication: United States NLM ID: 101504991 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1944-8252 (Electronic) Linking ISSN: 19448244 NLM ISO Abbreviation: ACS Appl Mater Interfaces Subsets: MEDLINE |
أسماء مطبوعة: | Original Publication: Washington, D.C. : American Chemical Society |
مواضيع طبية MeSH: | Durapatite*/chemistry , Durapatite*/pharmacology , Metal-Organic Frameworks*/chemistry , Metal-Organic Frameworks*/pharmacology , Agrochemicals*/chemistry , Agrochemicals*/pharmacology, Anti-Bacterial Agents/pharmacology ; Anti-Bacterial Agents/chemistry ; Nanoparticles/chemistry ; Zeolites/chemistry ; Zeolites/pharmacology ; Triticum/chemistry ; Triticum/drug effects ; Imidazoles |
مستخلص: | Although agrochemical practices can enhance agricultural productivity, their intensive application has resulted in the deterioration of ecosystems. Therefore, it is necessary to develop more efficient and less toxic methods against pests and infections while improving crop productivity. Moving toward sustainable development, in this work, we originally described the preparation of a composite (ZIF-8@HA) consisting of the coating of zeolitic-like metal-organic framework (MOF) ZIF-8 (based on Zn, an essential micronutrient in plants with antibacterial, antifungal, and antifouling properties) with hydroxyapatite (HA) nanoparticles (i.e., nanofertilizer). The interaction between the HA and ZIF-8 has been characterized through a combination of techniques, such as microscopic techniques, where the presence of a HA coating is demonstrated; or by analysis of the surface charge with a dramatic change in the Z-potential (from +18.7 ± 0.8 to -27.6 ± 0.7 mV for ZIF-8 and ZIF-8@HA, respectively). Interestingly, the interaction of HA with ZIF-8 delays the MOF degradation (from 4 h for pristine ZIF-8 to 168 h for HA-coated material), providing a slower and gradual release of zinc. After a comprehensive characterization, the potential combined fertilizer and bactericidal effect of ZIF-8@HA was investigated in wheat ( Triticum aestivum ) seeds and Pseudomonas syringae ( Ps ). ZIF-8@HA (7.3 ppm) demonstrated a great fertilizer effect, increasing shoot (9.4 %) and root length (27.1 %) of wheat seeds after 11 days at 25 °C under dark conditions, improving the results obtained with HA, ZIF-8, or ZnSO |
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فهرسة مساهمة: | Keywords: agriculture; antibacterial; fertilizer; hydroxyapatite; metal−organic frameworks |
المشرفين على المادة: | 91D9GV0Z28 (Durapatite) 0 (Metal-Organic Frameworks) 0 (Agrochemicals) 0 (ZIF-8 metal-organic framework) 0 (Anti-Bacterial Agents) 1318-02-1 (Zeolites) 0 (Imidazoles) |
تواريخ الأحداث: | Date Created: 20240527 Date Completed: 20240606 Latest Revision: 20240612 |
رمز التحديث: | 20240612 |
مُعرف محوري في PubMed: | PMC11163398 |
DOI: | 10.1021/acsami.4c06016 |
PMID: | 38798175 |
قاعدة البيانات: | MEDLINE |
تدمد: | 1944-8252 |
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DOI: | 10.1021/acsami.4c06016 |