دورية أكاديمية
أعرض في EDS

Exploring the solubility and intermolecular interactions of biologically significant amino acids l-serine and L-cysteine in binary mixtures of H 2 O + DMF, H 2 O + DMSO and H 2 O + ACN in temperature range from T = 288.15 K to 308.15 K.

التفاصيل البيبلوغرافية
العنوان: Exploring the solubility and intermolecular interactions of biologically significant amino acids l-serine and L-cysteine in binary mixtures of H 2 O + DMF, H 2 O + DMSO and H 2 O + ACN in temperature range from T = 288.15 K to 308.15 K.
المؤلفون: Chakraborty J; Department of Chemistry, University of Kalyani, Kalyani 741235, Nadia, India; Department of Chemistry, JIS College of Engineering, Kalyani 741235, Nadia, India., Mahali K; Department of Chemistry, University of Kalyani, Kalyani 741235, Nadia, India. Electronic address: gourkala@gmail.com., Henaish AMA; Physics Department, Faculty of Science, Tanta University, Tanta 31527, Egypt; NANOTECH Center, Ural Federal University, Ekaterinburg 620002, Russia., Ahmed J; Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia., Alshehri SM; Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia., Hossain A; Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, Russian Federation., Roy S; Department of Chemistry, School of Sciences, Netaji Subhas Open University, Kolkata, West Bengal, India. Electronic address: sanjayroyp@gmail.com.
المصدر: Biophysical chemistry [Biophys Chem] 2024 Aug; Vol. 311, pp. 107272. Date of Electronic Publication: 2024 May 27.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Elsevier Science B.V Country of Publication: Netherlands NLM ID: 0403171 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1873-4200 (Electronic) Linking ISSN: 03014622 NLM ISO Abbreviation: Biophys Chem Subsets: MEDLINE
أسماء مطبوعة: Publication: Amsterdam : Elsevier Science B.V
Original Publication: Amsterdam, North-Holland Pub. Co.
مواضيع طبية MeSH: Dimethyl Sulfoxide*/chemistry , Solubility* , Serine*/chemistry , Acetonitriles*/chemistry , Water*/chemistry , Cysteine*/chemistry , Dimethylformamide*/chemistry , Temperature*, Thermodynamics ; Solvents/chemistry
مستخلص: In the presented work, a study on the solubility and intermolecular interactions of l-serine and L-cysteine was carried out in binary mixtures of H 2 O + dimethylformamide (DMF), H 2 O + dimethylsulfoxide (DMSO), and H 2 O + acetonitrile (ACN) in the temperature range of T = 288.15 K to 308.15 K. l-serine exhibited the highest solubility in water, while L-cysteine was more soluble in water-DMF. The solvation process was assessed through standard Gibbs energy calculations, indicating the solvation stability order: water-ACN > water-DMSO > water-DMF for l-serine, and water-DMF > water-DMSO > water-ACN for L-cysteine. This study also explored the influence of these amino acids on solvent-solvent interactions, revealing changes in chemical entropies and self-association patterns within the binary solvent mixtures.
Competing Interests: Declaration of competing interest The authors did not disclose any potential conflict of interest.
(Copyright © 2024 Elsevier B.V. All rights reserved.)
فهرسة مساهمة: Keywords: Amino acids; Organic solvents; Solubility; Solution stability; Thermodynamics
المشرفين على المادة: YOW8V9698H (Dimethyl Sulfoxide)
452VLY9402 (Serine)
0 (Acetonitriles)
059QF0KO0R (Water)
K848JZ4886 (Cysteine)
Z072SB282N (acetonitrile)
8696NH0Y2X (Dimethylformamide)
0 (Solvents)
تواريخ الأحداث: Date Created: 20240602 Date Completed: 20240609 Latest Revision: 20240609
رمز التحديث: 20240610
DOI: 10.1016/j.bpc.2024.107272
PMID: 38824845
قاعدة البيانات: MEDLINE
الوصف
تدمد:1873-4200
DOI:10.1016/j.bpc.2024.107272