دورية أكاديمية
Co(III)-Catalyzed Regioselective Functionalization of Isoquinolones with Naphthoquinones.
| العنوان: | Co(III)-Catalyzed Regioselective Functionalization of Isoquinolones with Naphthoquinones. |
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| المؤلفون: | Sharma T; C-H Activation and Phytochemistry Lab, Chemical Technology Division, CSIR-IHBT, Palampur 176061, India., Sumit; C-H Activation and Phytochemistry Lab, Chemical Technology Division, CSIR-IHBT, Palampur 176061, India.; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India., Sachin; C-H Activation and Phytochemistry Lab, Chemical Technology Division, CSIR-IHBT, Palampur 176061, India.; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India., Chandra D; C-H Activation and Phytochemistry Lab, Chemical Technology Division, CSIR-IHBT, Palampur 176061, India., Gupta SS; C-H Activation and Phytochemistry Lab, Chemical Technology Division, CSIR-IHBT, Palampur 176061, India.; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India., Sharma U; C-H Activation and Phytochemistry Lab, Chemical Technology Division, CSIR-IHBT, Palampur 176061, India.; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India. |
| المصدر: | Organic letters [Org Lett] 2024 Jun 14; Vol. 26 (23), pp. 5027-5031. Date of Electronic Publication: 2024 Jun 03. |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: American Chemical Society Country of Publication: United States NLM ID: 100890393 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1523-7052 (Electronic) Linking ISSN: 15237052 NLM ISO Abbreviation: Org Lett Subsets: PubMed not MEDLINE; MEDLINE |
| أسماء مطبوعة: | Original Publication: Washington, DC : American Chemical Society, c1999- |
| مستخلص: | A strategy for Co(III)-catalyzed C(sp 2 )-H alkenylation of N -protected isoquinolones with 1,4-naphthoquinones has been disclosed. The developed protocol was efficiently applied for diversely substituted isoquinolones. Preliminary mechanistic experiments revealed the involvement of a five-membered cobaltacycle as an intermediate. Deuterium labeling experiments suggested the reversible nature of the C-H activation step. The scale-up reaction was also carried out, and the product was utilized as a chemosensor to detect Fe 3+ ions. |
| تواريخ الأحداث: | Date Created: 20240603 Latest Revision: 20240614 |
| رمز التحديث: | 20240614 |
| DOI: | 10.1021/acs.orglett.4c01686 |
| PMID: | 38829220 |
| قاعدة البيانات: | MEDLINE |
Find this issue from the American Chemical Society | تدمد: | 1523-7052 |
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| DOI: | 10.1021/acs.orglett.4c01686 |