دورية أكاديمية
The facile and controllable synthesis of ultrafine Sn nanocrystals loaded on carbon black for high-performance lithium storage.
| العنوان: | The facile and controllable synthesis of ultrafine Sn nanocrystals loaded on carbon black for high-performance lithium storage. |
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| المؤلفون: | Zhao Y; Harbin Engineering University, College of Materials Science and Chemical Engineering, CHINA., Li G; Harbin Engineering University, College of Materials Science and Chemical Engineering, CHINA., Kong X; Harbin Engineering University, College of Materials Science and Chemical Engineering, CHINA., Zhao X; Harbin Engineering University, College of Materials Science and Chemical Engineering, 145, 150001, CHINA., Liu L; Harbin Engineering University, College of Materials Science and Chemical Engineering, CHINA., Wang S; Harbin Engineering University, College of Materials Science and Chemical Engineering, CHINA., Li G; Qingdao University, College of Materials Science and Engineering, CHINA., Zhang M; Harbin Engineering University, College of Materials Science and Chemical Engineering, CHINA., Liu Z; Harbin Engineering University, College of Materials Science and Chemical Engineering, 145 Nantong Street, 150001, Harbin, CHINA., Yang P; Harbin Engineering University, College of Materials Science and Chemical Engineering, CHINA. |
| المصدر: | ChemSusChem [ChemSusChem] 2024 Jun 07, pp. e202301807. Date of Electronic Publication: 2024 Jun 07. |
| Publication Model: | Ahead of Print |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 101319536 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1864-564X (Electronic) Linking ISSN: 18645631 NLM ISO Abbreviation: ChemSusChem Subsets: MEDLINE |
| أسماء مطبوعة: | Original Publication: Weinheim : Wiley-VCH |
| مستخلص: | Sn and C nanocomposites are ideal anode materials for high-energy and high-power density lithium ion batteries. However, their facile and controllable synthesis for practical applications is still a critical challenge. In this work, a facile one-step method is developed to controllably synthesize ultrafine Sn nanocrystals (< 5 nm) loaded on carbon black (Sn@C) through Na reducing SnCl4 by mechanical milling. Different from traditional up-down mechanical milling method, this method utilizes mechanical milling to trigger bottom-up reduction reaction of SnCl4. The in-situ formed Sn nanocrystals directly grow on carbon black, which results in the homogeneous composite and the size control of Sn nanocrystals. The obtained Sn@C electrode is revealed to possesses large lithium diffusion coefficient, low lithiation energy barrier and stable electrochemical property during cycle, thus showing excellent lithium storage performance with a high reversible capacity (942 mAh g-1 at a current density of 100 mA g-1), distinguished rate ability (480 mAh g-1 at 8000 mA g-1) and superb cycling performance (730 mAh g-1 at 1000 mA g-1 even after 1000 cycles). (© 2024 Wiley‐VCH GmbH.) |
| فهرسة مساهمة: | Keywords: Sn nanocrystal; anode; carbon composite; facile synthesis; lithium storage |
| تواريخ الأحداث: | Date Created: 20240607 Latest Revision: 20240607 |
| رمز التحديث: | 20240607 |
| DOI: | 10.1002/cssc.202301807 |
| PMID: | 38847187 |
| قاعدة البيانات: | MEDLINE |
Full Text Finder | تدمد: | 1864-564X |
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| DOI: | 10.1002/cssc.202301807 |