دورية أكاديمية

The Facile and Controllable Synthesis of Ultrafine Sn Nanocrystals Loaded on Carbon Black for High-Performance Lithium Storage.

التفاصيل البيبلوغرافية
العنوان: The Facile and Controllable Synthesis of Ultrafine Sn Nanocrystals Loaded on Carbon Black for High-Performance Lithium Storage.
المؤلفون: Zhao Y; Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, 150001, P. R. China., Li G; Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, 150001, P. R. China., Kong X; Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, 150001, P. R. China., Zhao X; Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, 150001, P. R. China., Liu L; Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, 150001, P. R. China., Wang S; Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, 150001, P. R. China., Li G; Institute of Materials for Energy and Environment, College of Materials Science and Engineering, Qingdao University, Qingdao, 266071, P. R. China., Zhang M; Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, 150001, P. R. China., Liu Z; Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, 150001, P. R. China., Yang P; Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, 150001, P. R. China.
المصدر: ChemSusChem [ChemSusChem] 2024 Jun 07, pp. e202301807. Date of Electronic Publication: 2024 Jun 07.
Publication Model: Ahead of Print
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 101319536 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1864-564X (Electronic) Linking ISSN: 18645631 NLM ISO Abbreviation: ChemSusChem Subsets: MEDLINE
أسماء مطبوعة: Original Publication: Weinheim : Wiley-VCH
مستخلص: Sn and C nanocomposites are ideal anode materials for high-energy and high-power density lithium ion batteries. However, their facile and controllable synthesis for practical applications is still a critical challenge. In this work, a facile one-step method is developed to controllably synthesize ultrafine Sn nanocrystals (< 5 nm) loaded on carbon black (Sn@C) through Na reducing SnCl 4 by mechanical milling. Different from traditional up-down mechanical milling method, this method utilizes mechanical milling to trigger bottom-up reduction reaction of SnCl 4 . The in-situ formed Sn nanocrystals directly grow on carbon black, which results in the homogeneous composite and the size control of Sn nanocrystals. The obtained Sn@C electrode is revealed to possesses large lithium diffusion coefficient, low lithiation energy barrier and stable electrochemical property during cycle, thus showing excellent lithium storage performance with a high reversible capacity (942 mAh g -1 at a current density of 100 mA g -1 ), distinguished rate ability (480 mAh g -1 at 8000 mA g -1 ) and superb cycling performance (730 mAh g -1 at 1000 mA g -1 even after 1000 cycles).
(© 2024 Wiley-VCH GmbH.)
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معلومات مُعتمدة: 22101065 National Natural Science Foundation of China; 51972075 National Natural Science Foundation of China; YQ2021B001 Heilongjiang Provincial Natural Science Foundation of China; 2023T160153 China Postdoctoral Science Foundation; 2020M681075 China Postdoctoral Science Foundation; Fundamental Research Funds for the Central Universities
فهرسة مساهمة: Keywords: Sn nanocrystal; anode; carbon composite; facile synthesis; lithium storage
تواريخ الأحداث: Date Created: 20240607 Latest Revision: 20240731
رمز التحديث: 20240731
DOI: 10.1002/cssc.202301807
PMID: 38847187
قاعدة البيانات: MEDLINE