دورية أكاديمية
أعرض في EDS

Insight into uniform filming of LiF-rich interphase via synergistic adsorption for high-performance lithium metal anode.

التفاصيل البيبلوغرافية
العنوان: Insight into uniform filming of LiF-rich interphase via synergistic adsorption for high-performance lithium metal anode.
المؤلفون: He Y; Institute of Nuclear and New Energy Technology Tsinghua University Beijing China., Wang L; Institute of Nuclear and New Energy Technology Tsinghua University Beijing China., Wang A; Institute of Nuclear and New Energy Technology Tsinghua University Beijing China., Zhang B; Institute of Nuclear and New Energy Technology Tsinghua University Beijing China., Pham H; Department of Mechanical Engineering and Aerospace Engineering Missouri University of Science and Technology Rolla, MO USA., Park J; Department of Mechanical Engineering and Aerospace Engineering Missouri University of Science and Technology Rolla, MO USA., He X; Institute of Nuclear and New Energy Technology Tsinghua University Beijing China.
المصدر: Exploration (Beijing, China) [Exploration (Beijing)] 2023 Dec 22; Vol. 4 (2), pp. 20230114. Date of Electronic Publication: 2023 Dec 22 (Print Publication: 2024).
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: John Wiley & Sons Inc., Wiley Beijing Office in partnership with Henan University and Chinese Association of Nanobiology Country of Publication: China NLM ID: 9918383883006676 Publication Model: eCollection Cited Medium: Internet ISSN: 2766-2098 (Electronic) Linking ISSN: 27662098 NLM ISO Abbreviation: Exploration (Beijing) Subsets: PubMed not MEDLINE
أسماء مطبوعة: Original Publication: Beijing: John Wiley & Sons Inc., Wiley Beijing Office in partnership with Henan University and Chinese Association of Nanobiology, [2021]-
مستخلص: Multi-scale simulation is an important basis for constructing digital batteries to improve battery design and application. LiF-rich solid electrolyte interphase (SEI) is experimentally proven to be crucial for the electrochemical performance of lithium metal batteries. However, the LiF-rich SEI is sensitive to various electrolyte formulas and the fundamental mechanism is still unclear. Herein, the structure and formation mechanism of LiF-rich SEI in different electrolyte formulas have been reviewed. On this basis, it further discussed the possible filming mechanism of LiF-rich SEI determined by the initial adsorption of the electrolyte-derived species on the lithium metal anode (LMA). It proposed that individual LiF species follow the Volmer-Weber mode of film growth due to its poor wettability on LMA. Whereas, the synergistic adsorption of additive-derived species with LiF promotes the Frank-Vander Merwe mode of film growth, resulting in uniform LiF deposition on the LMA surface. This perspective provides new insight into the correlation between high LiF content, wettability of LiF, and highperformance of uniform LiF-rich SEI. It disclosed the importance of additive assistant synergistic adsorption on the uniform growth of LiF-rich SEI, contributing to the reasonable design of electrolyte formulas and high-performance LMA, and enlightening the way for multi-scale simulation of SEI.
Competing Interests: The authors declare no conflicts of interest.
(© 2023 The Authors. Exploration published by Henan University and John Wiley & Sons Australia, Ltd.)
References: Nat Commun. 2013;4:1481. (PMID: 23403582)
ACS Appl Mater Interfaces. 2022 Jul 13;:. (PMID: 35830236)
ACS Appl Mater Interfaces. 2018 May 30;10(21):17985-17993. (PMID: 29701458)
Nat Nanotechnol. 2021 May;16(5):549-554. (PMID: 33510453)
ACS Appl Mater Interfaces. 2023 Jan 11;15(1):1201-1209. (PMID: 36576328)
Nat Commun. 2020 May 6;11(1):2224. (PMID: 32376916)
J Am Chem Soc. 2023 Apr 12;145(14):8001-8006. (PMID: 36988463)
Adv Mater. 2020 Nov;32(46):e2002741. (PMID: 33035375)
Nat Commun. 2016 Jun 29;7:12032. (PMID: 27354162)
Chem Rev. 2014 Dec 10;114(23):11503-618. (PMID: 25351820)
J Am Chem Soc. 2013 Aug 14;135(32):11967-74. (PMID: 23901789)
Angew Chem Int Ed Engl. 2020 Jul 13;59(29):12147-12153. (PMID: 32237031)
Science. 2017 Oct 27;358(6362):506-510. (PMID: 29074771)
Angew Chem Int Ed Engl. 2023 Oct 16;62(42):e202306889. (PMID: 37442815)
Proc Natl Acad Sci U S A. 2020 Jan 7;117(1):73-79. (PMID: 31848237)
Small. 2020 Jul;16(30):e2001989. (PMID: 32521092)
Adv Sci (Weinh). 2015 Nov 17;3(3):1500213. (PMID: 27774393)
J Am Chem Soc. 2023 Jan 18;145(2):1327-1333. (PMID: 36576963)
Nano Lett. 2019 Aug 14;19(8):5140-5148. (PMID: 31322896)
ACS Appl Mater Interfaces. 2020 Jul 29;12(30):33719-33728. (PMID: 32608965)
Science. 2022 Jan 07;375(6576):66-70. (PMID: 34990230)
Nat Nanotechnol. 2019 Jan;14(1):50-56. (PMID: 30420761)
J Am Chem Soc. 2023 Jun 7;145(22):12342-12350. (PMID: 37220230)
Nat Mater. 2019 Apr;18(4):384-389. (PMID: 30858569)
Nat Nanotechnol. 2020 Mar;15(3):224-230. (PMID: 31988500)
Angew Chem Int Ed Engl. 2018 Jul 26;57(31):9795-9798. (PMID: 29947071)
Nat Nanotechnol. 2018 Aug;13(8):715-722. (PMID: 30013215)
Sci Adv. 2018 Dec 21;4(12):eaau9245. (PMID: 30588493)
Nat Commun. 2015 Jun 17;6:7436. (PMID: 26081242)
Nature. 2018 Aug;560(7718):345-349. (PMID: 30111789)
Angew Chem Int Ed Engl. 2018 May 4;57(19):5301-5305. (PMID: 29465827)
ACS Appl Mater Interfaces. 2022 Feb 16;14(6):7972-7979. (PMID: 35129322)
Nat Mater. 2014 Oct;13(10):961-9. (PMID: 25108613)
Nano Lett. 2017 Dec 13;17(12):7606-7612. (PMID: 29090936)
Adv Mater. 2020 Mar;32(12):e1906427. (PMID: 32058645)
فهرسة مساهمة: Keywords: LiF‐rich solid electrolyte interphase; additive‐derived species; film growth mechanism; lithium metal anode; synergistic adsorption
تواريخ الأحداث: Date Created: 20240610 Latest Revision: 20240611
رمز التحديث: 20240611
مُعرف محوري في PubMed: PMC11022620
DOI: 10.1002/EXP.20230114
PMID: 38855613
قاعدة البيانات: MEDLINE
الوصف
تدمد:2766-2098
DOI:10.1002/EXP.20230114