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Accelerated Conversion of Polysulfides for Ultra Long-Cycle of Li-S Battery at High-Rate over Cooperative Cathode Electrocatalyst of Ni 0.261 Co 0.739 S 2 /N-Doped CNTs.

التفاصيل البيبلوغرافية
العنوان: Accelerated Conversion of Polysulfides for Ultra Long-Cycle of Li-S Battery at High-Rate over Cooperative Cathode Electrocatalyst of Ni 0.261 Co 0.739 S 2 /N-Doped CNTs.
المؤلفون: Ji J; Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), 77 Cheongam-ro, Nam-gu, Pohang-si, Gyeongsangbuk-do, 37673, Republic of Korea., Park M; Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), 77 Cheongam-ro, Nam-gu, Pohang-si, Gyeongsangbuk-do, 37673, Republic of Korea., Kim M; Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), 77 Cheongam-ro, Nam-gu, Pohang-si, Gyeongsangbuk-do, 37673, Republic of Korea., Kang SK; Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), 77 Cheongam-ro, Nam-gu, Pohang-si, Gyeongsangbuk-do, 37673, Republic of Korea., Park GH; Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), 77 Cheongam-ro, Nam-gu, Pohang-si, Gyeongsangbuk-do, 37673, Republic of Korea., Maeng J; Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), 77 Cheongam-ro, Nam-gu, Pohang-si, Gyeongsangbuk-do, 37673, Republic of Korea., Ha J; Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), 77 Cheongam-ro, Nam-gu, Pohang-si, Gyeongsangbuk-do, 37673, Republic of Korea., Seo MH; Department of Nanotechnology Engineering, Pukyong National University (PKNU), 45 Yongso-ro, Nam-gu, Busan-si, 48513, Republic of Korea., Kim WB; Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), 77 Cheongam-ro, Nam-gu, Pohang-si, Gyeongsangbuk-do, 37673, Republic of Korea.; Graduate Institute of Ferrous & Eco Materials Technology, Pohang University of Science and Technology (POSTECH), 77 Cheongam-ro, Nam-gu, Pohang-si, Gyeongsangbuk-do, 37673, Republic of Korea.
المصدر: Advanced science (Weinheim, Baden-Wurttemberg, Germany) [Adv Sci (Weinh)] 2024 Jun 12, pp. e2402389. Date of Electronic Publication: 2024 Jun 12.
Publication Model: Ahead of Print
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: WILEY-VCH Country of Publication: Germany NLM ID: 101664569 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 2198-3844 (Electronic) Linking ISSN: 21983844 NLM ISO Abbreviation: Adv Sci (Weinh) Subsets: MEDLINE
أسماء مطبوعة: Original Publication: Weinheim : WILEY-VCH, [2014]-
مستخلص: Despite the very high theoretical energy density, Li-S batteries still need to fundamentally overcome the sluggish redox kinetics of lithium polysulfides (LiPSs) and low sulfur utilization that limit the practical applications. Here, highly active and stable cathode, nitrogen-doped porous carbon nanotubes (NPCTs) decorated with Ni x Co 1-x S 2 nanocrystals are systematically synthesized as multi-functional electrocatalytic materials. The nitrogen-doped carbon matrix can contribute to the adsorption of LiPSs on heteroatom active sites with buffering space. Also, both experimental and computation-based theoretical analyses validate the electrocatalytic principles of co-operational facilitated redox reaction dominated by covalent-site-dependent mechanism; the favorable adsorption-interaction and electrocatalytic conversion of LiPSs take place subsequently by weakening sulfur-bond strength on the catalytic Ni Oh 2+ -S-Co Oh 2+ backbones via octahedral TM-S (TM = Ni, Co) covalency-relationship, demonstrating that fine tuning of Co Oh 2+ sites by Ni Oh 2+ substitution effectively modulates the binding energies of LiPSs on the Ni x Co 1-x S 2 @NPCTs surface. Noteworthy, the Ni 0.261 Co 0.739 S 2 @NPCTs catalyst shows great cyclic stability with a capacity of up to 511 mAh g -1 and only 0.055% decay per cycle at 5.0 C during 1000 cycles together with a high areal capacity of 2.20 mAh cm -2 under 4.61 mg cm -2 sulfur loading even after 200 cycles at 0.2 C. This strategy highlights a new perspective for achieving high-energy-density Li-S batteries.
(© 2024 The Author(s). Advanced Science published by Wiley‐VCH GmbH.)
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معلومات مُعتمدة: National Research Foundation of Korea; Ministry of Trade, Industry & Energy; 20012224 Ministry of Trade, Industry and Energy; 2021R1A5A1084921 Ministry of Science and ICT, South Korea; 2019R1A2C2088174 Ministry of Science and ICT, South Korea; Education Program for Innovative Chemical Engineering Leaders; BK21 FOUR Program for Education Program for Innovative Chemical Engineering Leaders of the National Research Foundation of Korea (NRF)
فهرسة مساهمة: Keywords: Li‐S battery; N‐doped porous carbon; cooperative cathode catalysts; lithium polysulfides; nickel cobalt sulfide
تواريخ الأحداث: Date Created: 20240613 Latest Revision: 20240613
رمز التحديث: 20240613
DOI: 10.1002/advs.202402389
PMID: 38867385
قاعدة البيانات: MEDLINE
الوصف
تدمد:2198-3844
DOI:10.1002/advs.202402389