Molecular Engineering Regulation Achieving Out-of-Plane Polarization in Rare-Earth Hybrid Double Perovskites for Ferroelectrics and Circularly Polarized Luminescence.

التفاصيل البيبلوغرافية
العنوان:	Molecular Engineering Regulation Achieving Out-of-Plane Polarization in Rare-Earth Hybrid Double Perovskites for Ferroelectrics and Circularly Polarized Luminescence.
المؤلفون:	Wang N; Chaotic Matter Science Research Center, Jiangxi Province Key Laboratory of Functional Crystalline Materials Chemistry, International Institute for Innovation, Jiangxi, University of Science and Technology, Ganzhou, 341000, P.R. China., Xu ZJ; Chaotic Matter Science Research Center, Jiangxi Province Key Laboratory of Functional Crystalline Materials Chemistry, International Institute for Innovation, Jiangxi, University of Science and Technology, Ganzhou, 341000, P.R. China., Ni HF; Institute for Science and Applications of Molecular Ferroelectrics, Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua, 321004, P.R. China., Luo W; Chaotic Matter Science Research Center, Jiangxi Province Key Laboratory of Functional Crystalline Materials Chemistry, International Institute for Innovation, Jiangxi, University of Science and Technology, Ganzhou, 341000, P.R. China., Li HK; Chaotic Matter Science Research Center, Jiangxi Province Key Laboratory of Functional Crystalline Materials Chemistry, International Institute for Innovation, Jiangxi, University of Science and Technology, Ganzhou, 341000, P.R. China., Ren ML; Chaotic Matter Science Research Center, Jiangxi Province Key Laboratory of Functional Crystalline Materials Chemistry, International Institute for Innovation, Jiangxi, University of Science and Technology, Ganzhou, 341000, P.R. China., Shi C; Chaotic Matter Science Research Center, Jiangxi Province Key Laboratory of Functional Crystalline Materials Chemistry, International Institute for Innovation, Jiangxi, University of Science and Technology, Ganzhou, 341000, P.R. China., Ye HY; Chaotic Matter Science Research Center, Jiangxi Province Key Laboratory of Functional Crystalline Materials Chemistry, International Institute for Innovation, Jiangxi, University of Science and Technology, Ganzhou, 341000, P.R. China., Fu XB; Department of Molten Salt Chemistry and Engineering, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, 201800, China., Zhang Y; Institute for Science and Applications of Molecular Ferroelectrics, Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua, 321004, P.R. China., Miao LP; Chaotic Matter Science Research Center, Jiangxi Province Key Laboratory of Functional Crystalline Materials Chemistry, International Institute for Innovation, Jiangxi, University of Science and Technology, Ganzhou, 341000, P.R. China.
المصدر:	Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2024 Jul 03, pp. e202409796. Date of Electronic Publication: 2024 Jul 03.
Publication Model:	Ahead of Print
نوع المنشور:	Journal Article
اللغة:	English
بيانات الدورية:	Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 0370543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-3773 (Electronic) Linking ISSN: 14337851 NLM ISO Abbreviation: Angew Chem Int Ed Engl Subsets: MEDLINE
أسماء مطبوعة:	Publication: <2004-> : Weinheim : Wiley-VCH Original Publication: Weinheim/Bergstr. : New York, : Verlag Chemie ; Academic Press, c1962-
مستخلص:	Out-of-plane polarization is a highly desired property of two-dimensional (2D) ferroelectrics for application in vertical sandwich-type photoferroelectric devices, especially in ultrathin ferroelectronic devices. Nevertheless, despite great advances that have been made in recent years, out-of-plane polarization remains unrealized in the 2D hybrid double perovskite ferroelectric family. Here, from our previous work 2D hybrid double perovskite HQERN ((S3HQ) 4 EuRb(NO 3 ) 8 , S3HQ=S-3-hydroxylquinuclidinium), we designed a molecular strategy of F-substitution on organic component to successfully obtain FQERN ((S3FQ) 4 EuRb(NO 3 ) 8 , S3FQ=S-3-fluoroquinuclidinium) showing circularly polarized luminescence (CPL) response. Remarkably, compared to the monopolar axis ferroelectric HQERN, FQERN not only shows multiferroicity with the coexistence of multipolar axis ferroelectricity and ferroelasticity but also realizes out-of-plane ferroelectric polarization and a dramatic enhancement of Curie temperature of 94 K. This is mainly due to the introduction of F-substituted organic cations, which leads to a change in orientation and a reduction in crystal lattice void occupancy. Our study demonstrates that F-substitution is an efficient strategy to realize and optimize ferroelectric functional characteristics, giving more possibility of 2D ferroelectric materials for applications in micro-nano optoelectronic devices. (© 2024 Wiley-VCH GmbH.)
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معلومات مُعتمدة:	22371095 National Natural Science Foundation of China; 22205087 National Natural Science Foundation of China; 92056112 National Natural Science Foundation of China; 22375182 National Natural Science Foundation of China; 21875093 National Natural Science Foundation of China; 22175079 National Natural Science Foundation of China; LZ24B010001 Natural Science Foundation of Zhejiang Province
فهرسة مساهمة:	Keywords: circularly polarized luminescence; ferroelectric; molecular engineering; out-of-plane polarization; rare-earth hybrid double perovskites
تواريخ الأحداث:	Date Created: 20240703 Latest Revision: 20240820
رمز التحديث:	20240820
DOI:	10.1002/anie.202409796
PMID:	38958031
قاعدة البيانات:	MEDLINE

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تدمد:	1521-3773
DOI:	10.1002/anie.202409796