Asymmetric catalytic synthesis of chiral covalent organic framework composite (S)-DTP-COF@SiO 2 for HPLC enantioseparations by normal-phase and reversed-phase chromatographic modes.

التفاصيل البيبلوغرافية
العنوان:	Asymmetric catalytic synthesis of chiral covalent organic framework composite (S)-DTP-COF@SiO 2 for HPLC enantioseparations by normal-phase and reversed-phase chromatographic modes.
المؤلفون:	Zhou HM; Department of Chemistry, Yunnan Normal University, Kunming, 650500, PR China., Liu C; Department of Chemistry, Yunnan Normal University, Kunming, 650500, PR China., Zhang Y; Department of Chemistry, Yunnan Normal University, Kunming, 650500, PR China., Ma AX; Department of Chemistry, Yunnan Normal University, Kunming, 650500, PR China., Luo ZH; Department of Chemistry, Yunnan Normal University, Kunming, 650500, PR China., Zhu YL; Department of Chemistry, Yunnan Normal University, Kunming, 650500, PR China., Ran XY; Department of Chemistry, Yunnan Normal University, Kunming, 650500, PR China., Xie SM; Department of Chemistry, Yunnan Normal University, Kunming, 650500, PR China. xieshengming_2006@163.com., Wang BJ; Department of Chemistry, Yunnan Normal University, Kunming, 650500, PR China. wangbangjin711@163.com., Zhang JH; Department of Chemistry, Yunnan Normal University, Kunming, 650500, PR China. zjh19861202@126.com., Yuan LM; Department of Chemistry, Yunnan Normal University, Kunming, 650500, PR China.
المصدر:	Mikrochimica acta [Mikrochim Acta] 2024 Jul 03; Vol. 191 (8), pp. 445. Date of Electronic Publication: 2024 Jul 03.
نوع المنشور:	Journal Article
اللغة:	English
بيانات الدورية:	Publisher: Springer-Verlag Country of Publication: Austria NLM ID: 7808782 Publication Model: Electronic Cited Medium: Internet ISSN: 1436-5073 (Electronic) Linking ISSN: 00263672 NLM ISO Abbreviation: Mikrochim Acta Subsets: PubMed not MEDLINE; MEDLINE
أسماء مطبوعة:	Original Publication: Wien ; New York : Springer-Verlag.
مستخلص:	A novel CCOF core-shell composite material (S)-DTP-COF@SiO 2 was prepared via asymmetric catalytic and in situ growth strategy. The prepared (S)-DTP-COF@SiO 2 was utilized as separation medium for HPLC enantioseparation using normal-phase and reversed-phase chromatographic modes, which displays excellent chiral separation performance for alcohols, esters, ketones, and epoxides, etc. Compared with chiral commercial chromatographic columns (Chiralpak AD-H and Chiralcel OD-H columns) and some previously reported chiral CCOF@SiO 2 (CC-MP CCTF@SiO 2 and MDI-β-CD-modified COF@SiO 2 )-packed columns, there are 4, 3, 13, and 15 tested racemic compounds that could not be resolved on the Chiralpak AD-H column, Chiralcel OD-H column, CC-MP CCTF@SiO 2 column, and MDI-β-CD-modified COF@SiO 2 column, respectively, which indicates that the resolution effect of (S)-DTP-COF@SiO 2 -packed column can be complementary to the other ones. The effects of the analyte mass, column temperature, and mobile phase composition on the enantiomeric separation were investigated. The chiral column exhibits good reproducibility after multiple consecutive injections. The RSDs (n = 5) of the peak area and retention time were less than 1.5% for repetitive separation of 2-methoxy-2-phenylethanol and 1-phenyl-1-pentanol. The chiral core-shell composite (S)-DTP-COF@SiO 2 exhibited good enantiomeric separation performance, which not only demonstrates its potential as a novel CSP material in HPLC but also expands the range of applications for chiral COFs. (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, part of Springer Nature.)
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معلومات مُعتمدة:	22364022 National Natural Science Foundation of China; 21964021 National Natural Science Foundation of China; 22064020 National Natural Science Foundation of China; 202201AT070029 Applied Basic Research Foundation of Yunnan Province; 202101AT070101 Applied Basic Research Foundation of Yunnan Province
فهرسة مساهمة:	Keywords: Asymmetric catalytic synthesis; Chiral covalent organic frameworks; Enantioseparation; HPLC
تواريخ الأحداث:	Date Created: 20240703 Latest Revision: 20240813
رمز التحديث:	20240813
DOI:	10.1007/s00604-024-06524-9
PMID:	38958767
قاعدة البيانات:	MEDLINE

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تدمد:	1436-5073
DOI:	10.1007/s00604-024-06524-9