دورية أكاديمية

Red-emitting 4-methyl coumarin fused barbituric acid as an electrochemical sensor for catechol detection and probe for latent fingerprints.

التفاصيل البيبلوغرافية
العنوان: Red-emitting 4-methyl coumarin fused barbituric acid as an electrochemical sensor for catechol detection and probe for latent fingerprints.
المؤلفون: Yashyanaik S; Department of P.G. Studies and Research in Chemistry, Kuvempu University, Jnanasahyadri, Shankaraghatta, Karnataka, India., Venkatesh T; Department of P.G. Studies and Research in Chemistry, Kuvempu University, Jnanasahyadri, Shankaraghatta, Karnataka, India., Ereshnaik; Department of P.G. Studies and Research in Industrial Chemistry, Sir. M.V. Govt. Science College, Bommanakatte, Bhadravathi, Karnataka, India., Vinuth M; Department of Chemistry, The National Institute of Engineering, North campus, Mysore, Karnataka, India.
المصدر: Luminescence : the journal of biological and chemical luminescence [Luminescence] 2024 Jul; Vol. 39 (7), pp. e4825.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Wiley & Sons Country of Publication: England NLM ID: 100889025 Publication Model: Print Cited Medium: Internet ISSN: 1522-7243 (Electronic) Linking ISSN: 15227235 NLM ISO Abbreviation: Luminescence Subsets: MEDLINE
أسماء مطبوعة: Original Publication: Chichester, Sussex, UK : Wiley & Sons, c1999-
مواضيع طبية MeSH: Barbiturates*/chemistry , Catechols*/chemistry , Catechols*/analysis , Electrochemical Techniques*/instrumentation , Coumarins*/chemistry, Fluorescent Dyes/chemistry ; Fluorescent Dyes/chemical synthesis ; Molecular Structure ; Density Functional Theory ; Electrodes
مستخلص: Herein, we have reported a red-emitting 4-methyl coumarin fused barbituric acid azo dye (4-MCBA) synthesized by conventional method. Density functional theory (DFT) studies of tautomer compounds were done using (B3LYP) with a basis set of 6-31G(d,p). NLO analysis has shown that tautomer has mean first-order hyperpolarisabilities (β) value of 1.8188 × 10 -30  esu and 1.0470 × 10 -30  esu for azo and hydrazone forms, respectively, which is approximately nine and five times greater than the magnitude of urea. 4-MCBA exhibited two absorption peaks in the range of 290-317 and 379-394 nm, and emission spectra were observed at 536 nm. CV study demonstrated that the modified 4-MCBA/MGC electrode exhibited excellent electrochemical sensitivity towards the detection of catechol and the detection limit is 9.39 μM under optimum conditions. The 4-MCBA employed as a fluorescent probe for the visualisation of LFPs on various surfaces exhibited Level-I to level-II LFPs, with low background interference.
(© 2024 John Wiley & Sons Ltd.)
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فهرسة مساهمة: Keywords: 4‐methyl coumarin; DFT; LFPs; NLO; electrochemical sensor
المشرفين على المادة: 0 (Barbiturates)
WQ92Y2793G (barbituric acid)
0 (Catechols)
0 (Coumarins)
LF3AJ089DQ (catechol)
0 (Fluorescent Dyes)
تواريخ الأحداث: Date Created: 20240704 Date Completed: 20240704 Latest Revision: 20240726
رمز التحديث: 20240726
DOI: 10.1002/bio.4825
PMID: 38961763
قاعدة البيانات: MEDLINE
الوصف
تدمد:1522-7243
DOI:10.1002/bio.4825