التفاصيل البيبلوغرافية
| العنوان: |
From Pb 6 (HPO 3 )(H 2 PO 3 )Cl 9 to Pb 6 (HPO 3 ) 2 Br 8 (H 2 O)·H 2 O: Halogen Regulation to Achieve Inorganic Metal Phosphite Halide Nonlinear Optical Material with Unprecedented Pb-Centered Polyhedral Units. |
| المؤلفون: |
Tang RL; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, People's Republic of China., Ma L; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, People's Republic of China., Lv YL; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, People's Republic of China., Liu W; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, People's Republic of China., Guo SP; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, People's Republic of China. |
| المصدر: |
Inorganic chemistry [Inorg Chem] 2024 Jul 22; Vol. 63 (29), pp. 13197-13201. Date of Electronic Publication: 2024 Jul 08. |
| نوع المنشور: |
Journal Article |
| اللغة: |
English |
| بيانات الدورية: |
Publisher: American Chemical Society Country of Publication: United States NLM ID: 0366543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-510X (Electronic) Linking ISSN: 00201669 NLM ISO Abbreviation: Inorg Chem Subsets: PubMed not MEDLINE; MEDLINE |
| أسماء مطبوعة: |
Original Publication: [Easton, Pa.] American Chemical Society. |
| مستخلص: |
Nonlinear optical (NLO) crystals are widely used in various fields. The introduction of lone-pair cations is regarded as an effective strategy to explore NLO crystals. In this work, two novel lead phosphite halides, centrosymmetric Pb 6 (HPO 3 )(H 2 PO 3 )Cl 9 and noncentrosymmetric Pb 6 (HPO 3 ) 2 Br 8 (H 2 O)·H 2 O, were obtained via a hydrothermal method. Pb 6 (HPO 3 )(H 2 PO 3 )Cl 9 is the first reported lone-pair metal phosphite with two kinds of phosphite groups (HPO 3 2- and H 2 PO 3 - ) and Pb 6 (HPO 3 ) 2 Br 8 (H 2 O)·H 2 O is the first inorganic NLO phosphite halide with a phase-matchable SHG effect of 1.02 × KDP. In addition, the Pb-centered polyhedral units of PbOCl 4 , PbOCl 6 , PbO 2 Cl 5 , PbO 2 Br 5 , PbOBr 6 , and PbO 3 (H 2 O)Br 3 in these two structures have never been reported before. An in-depth study on the structure-property relationship of the two compounds with halogen substitution is also performed. |
| تواريخ الأحداث: |
Date Created: 20240708 Latest Revision: 20240722 |
| رمز التحديث: |
20240722 |
| DOI: |
10.1021/acs.inorgchem.4c02401 |
| PMID: |
38975741 |
| قاعدة البيانات: |
MEDLINE |
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