دورية أكاديمية
أعرض في EDS

Sustainable and Biomimetic Methodology for Extraction of High-Value-Added Compounds in Almond Hulls.

التفاصيل البيبلوغرافية
العنوان: Sustainable and Biomimetic Methodology for Extraction of High-Value-Added Compounds in Almond Hulls.
المؤلفون: Cremasco G; Institute of Chemistry, São Paulo State University (UNESP), R. Prof. Francisco Degni 55, Araraquara 14800-900, SP, Brazil., Sutton AT; Future Industries Institute, Mawson Lakes Campus, University of South Australia, Adelaide, SA 5095, Australia., Funari CS; Green Biotech Network, School of Agricultural Sciences, São Paulo State University (UNESP), Av. Universitária, nº 3780-Altos do Paraíso, Botucatu 18610-034, SP, Brazil., Arrua DR; Future Industries Institute, Mawson Lakes Campus, University of South Australia, Adelaide, SA 5095, Australia., Dussan KJ; Institute of Chemistry, São Paulo State University (UNESP), R. Prof. Francisco Degni 55, Araraquara 14800-900, SP, Brazil., Hilder EF; Future Industries Institute, Mawson Lakes Campus, University of South Australia, Adelaide, SA 5095, Australia., Bolzani VS; Institute of Chemistry, São Paulo State University (UNESP), R. Prof. Francisco Degni 55, Araraquara 14800-900, SP, Brazil., Rinaldo D; Institute of Chemistry, São Paulo State University (UNESP), R. Prof. Francisco Degni 55, Araraquara 14800-900, SP, Brazil.; Green Biotech Network, School of Sciences, São Paulo State University (UNESP), Av. Eng. Luiz Edmundo Carrijo Coube 14-01, Bauru 17033-360, SP, Brazil.
المصدر: Molecules (Basel, Switzerland) [Molecules] 2024 Jun 26; Vol. 29 (13). Date of Electronic Publication: 2024 Jun 26.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: MDPI Country of Publication: Switzerland NLM ID: 100964009 Publication Model: Electronic Cited Medium: Internet ISSN: 1420-3049 (Electronic) Linking ISSN: 14203049 NLM ISO Abbreviation: Molecules Subsets: MEDLINE
أسماء مطبوعة: Original Publication: Basel, Switzerland : MDPI, c1995-
مواضيع طبية MeSH: Prunus dulcis*/chemistry , Plant Extracts*/chemistry , Plant Extracts*/isolation & purification, Microwaves ; Green Chemistry Technology/methods ; Solvents/chemistry ; Biomimetics ; Nuts/chemistry
مستخلص: Almond trees are the most cultivated nut tree in the world. The production of almonds generates large amounts of by-products, much of which goes unused. Herein, this study aimed to develop a green chemistry approach to identify and extract potentially valuable compounds from almond by-products. Initially, a screening was performed with 10 different Natural Deep Eutectic Solvents (NADESs). The mixture lactic acid/glycerol, with a molar ratio 1:1 (1:50 plant material to NADES ( w / v ) with 20% v / v of water) was identified as the best extraction solvent for catechin, caffeoylquinic acid, and condensed tannins in almond hulls. Subsequently, a method was optimized by a Design of Experiment (DoE) protocol using a miniaturized extraction technique, Microwave-Assisted Extraction (MAE), in conjunction with the chosen NADESs. The optimal conditions were found to be 70 °C with 15 min irradiation time. The optimal extraction conditions determined by the DoE were confirmed experimentally and compared to methods already established in the literature. With these conditions, the extraction of metabolites was 2.4 times higher, according to the increase in total peak area, than the established literature methods used. Additionally, by applying the multiparameter Analytical Greenness Metric (AGREE) and Green Analytical Process Index (GAPI) metrics, it was possible to conclude that the developed method was greener than the established literature methods as it includes various principles of green analytical chemistry.
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معلومات مُعتمدة: 2014/50926-0 Fundação de Amparo à Pesquisa do Estado de São Paulo; 2018/50025-3 Fundação de Amparo à Pesquisa do Estado de São Paulo; 465637/2014-0 Institutos Nacionais de Ciência e Tecnologia; 2020/15024-6 Fundação de Amparo à Pesquisa do Estado de São Paulo
فهرسة مساهمة: Keywords: Microwave-Assisted Extraction; NADESs; Prunus dulcis; design of experiments; green chemistry
المشرفين على المادة: 0 (Plant Extracts)
0 (Solvents)
تواريخ الأحداث: Date Created: 20240713 Date Completed: 20240713 Latest Revision: 20240715
رمز التحديث: 20240715
مُعرف محوري في PubMed: PMC11243185
DOI: 10.3390/molecules29133034
PMID: 38998984
قاعدة البيانات: MEDLINE
الوصف
تدمد:1420-3049
DOI:10.3390/molecules29133034