دورية أكاديمية
van der Waals gap modulation of graphene oxide through mono-Boc ethylenediamine anchoring for superior Li-ion batteries.
| العنوان: | van der Waals gap modulation of graphene oxide through mono-Boc ethylenediamine anchoring for superior Li-ion batteries. |
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| المؤلفون: | Mandal S; Department of Chemistry, Indian Institute of Science Education and Research (IISER) Tirupati Andhra Pradesh 517507 India vijay@iisertirupati.ac.in., Pillai VK; Department of Chemistry, Indian Institute of Science Education and Research (IISER) Tirupati Andhra Pradesh 517507 India vijay@iisertirupati.ac.in., Ranjana Ponraj M; Department of Applied Chemistry, Karunya Institute of Technology and Sciences Coimbatore Tamil Nadu 641114 India jebasinghb@karunya.edu., K M T; Department of Applied Chemistry, Karunya Institute of Technology and Sciences Coimbatore Tamil Nadu 641114 India jebasinghb@karunya.edu., Bhagavathsingh J; Department of Applied Chemistry, Karunya Institute of Technology and Sciences Coimbatore Tamil Nadu 641114 India jebasinghb@karunya.edu., Grage SL; Karlsruhe Institute of Technology, Institute of Biological Interfaces IBG-2 P.O. Box 3640 76021 Karlsruhe Germany., Peng X; College of Integrative Sciences and Arts, Arizona State University Mesa AZ 85212 USA., Kang JW; Laser Biomedical Research Centre, G. R. Harrison Spectroscopy Laboratory, Massachusetts Institute of Technology Cambridge Massachusetts 02139 USA., Liepmann D; Department of Bioengineering, University of California 80 Hearst Memorial Mining Bldg. Berkeley CA 94720 USA., Kannan ANM; The Polytechnic School, Ira A. Fulton Schools of Engineering, Arizona State University Mesa AZ 85212 USA., Thavasi V; Center for Quantum Research and Technology, The University of Oklahoma 440 W. Brooks Street Normon OK 73019 USA., Renugopalakrishnan V; Department of Chemistry, Boston Children's Hospital, Harvard Medical School, MGB Center for COVID Innovation, Northeastern University Boston MA 02115 USA. |
| المصدر: | Energy advances [Energy Adv] 2024 Jun 21; Vol. 3 (8), pp. 1977-1991. Date of Electronic Publication: 2024 Jun 21 (Print Publication: 2024). |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 9918402280506676 Publication Model: eCollection Cited Medium: Internet ISSN: 2753-1457 (Electronic) Linking ISSN: 27531457 NLM ISO Abbreviation: Energy Adv Subsets: PubMed not MEDLINE |
| أسماء مطبوعة: | Original Publication: [Cambridge] : Royal Society of Chemistry, [2022]- |
| مستخلص: | Li-ion batteries stand out among energy storage systems due to their higher energy and power density, cycle life, and high-rate performance. Development of advanced, high-capacity anodes is essential for enhancing their performance, safety, and durability, and recently, two-dimensional materials have garnered extensive attention in this regard due to distinct properties, particularly their ability to modulate van der Waals gap through intercalation. Covalently intercalated Graphene oxide interlayer galleries with mono-Boc-ethylenediamine (GO-EnBoc) was synthesized via the ring opening of epoxide, forming an amino alcohol moiety. This creates three coordination sites for Li ion exchange on the graphene oxide nanosheets' surface. Consequently, the interlayer d -spacing expands from 8.47 Å to 13.17 Å, as anticipated. When explored as an anode, Li-GO-EnBoc shows a significant enhancement in the stable and reversible capacity of 270 mA h g -1 at a current density of 25 mA g -1 compared to GO (80 mA h g -1 ), without compromising the mechanical or chemical stability. Through 13 C, 7 Li and 6 Li MAS NMR, XPS, IR, Raman microscopy, and density functional theory (DFT) calculations, we confirm the positioning of Li + ions at multiple sites of the interlayer gallery, which enhances the electrochemical performance. Our findings suggest that these novel systematically modulated van der Waals gap GO-engineered materials hold promise as efficient anodes for Li-ion batteries. Competing Interests: The authors are not involved in conflict of interest. (This journal is © The Royal Society of Chemistry.) |
| References: | Science. 2015 Jan 2;347(6217):1246501. (PMID: 25554791) Sci Adv. 2021 May 28;7(22):. (PMID: 34049889) ACS Nano. 2021 Dec 28;15(12):18931-18973. (PMID: 34860483) J Am Chem Soc. 2023 Nov 8;145(44):24218-24229. (PMID: 37874900) Nat Mater. 2015 Mar;14(3):271-9. (PMID: 25532074) J Chem Phys. 2010 Apr 21;132(15):154104. (PMID: 20423165) ACS Nano. 2009 Sep 22;3(9):2547-56. (PMID: 19689122) Phys Rev B Condens Matter. 1994 Dec 15;50(24):17953-17979. (PMID: 9976227) Proc Natl Acad Sci U S A. 2020 Dec 1;117(48):30135-30141. (PMID: 33199622) Adv Mater. 2013 Apr 18;25(15):2152-7. (PMID: 23427163) RSC Adv. 2021 Aug 18;11(45):27925-27936. (PMID: 35480766) Nano Lett. 2008 Aug;8(8):2277-82. (PMID: 18651781) Nat Commun. 2019 Jan 17;10(1):275. (PMID: 30655526) J Nanosci Nanotechnol. 2009 Mar;9(3):1665-78. (PMID: 19435024) Nano Lett. 2010 Mar 10;10(3):751-8. (PMID: 20085345) Sci Rep. 2019 Dec 20;9(1):19480. (PMID: 31862907) ACS Nano. 2011 Jun 28;5(6):4345-9. (PMID: 21609023) Sci Rep. 2017 Jul 7;7(1):4886. (PMID: 28687731) Nature. 2008 Feb 7;451(7179):652-7. (PMID: 18256660) Nat Commun. 2020 Oct 2;11(1):4976. (PMID: 33009387) Nano Lett. 2008 Jan;8(1):307-9. (PMID: 18095738) Small. 2015 Jul;11(28):3451-7. (PMID: 25757440) J Magn Reson. 2011 Dec;213(2):413-7. (PMID: 22152360) Adv Mater. 2021 Nov;33(47):e2004689. (PMID: 33448099) Phys Rev B Condens Matter. 1996 Oct 15;54(16):11169-11186. (PMID: 9984901) Nanoscale. 2017 Feb 16;9(7):2585-2595. (PMID: 28150823) Proc Natl Acad Sci U S A. 2012 Oct 23;109(43):17360-5. (PMID: 23045691) ACS Appl Mater Interfaces. 2021 Mar 31;13(12):14786-14795. (PMID: 33739082) Nat Nanotechnol. 2017 Mar 7;12(3):194-206. (PMID: 28265117) Nano Lett. 2010 Sep 8;10(9):3386-8. (PMID: 20677788) ACS Appl Mater Interfaces. 2018 May 23;10(20):17183-17194. (PMID: 29708718) Nat Commun. 2020 Dec 8;11(1):6279. (PMID: 33293543) Phys Rev Lett. 1996 Oct 28;77(18):3865-3868. (PMID: 10062328) Nat Mater. 2009 Feb;8(2):120-5. (PMID: 19151701) Chem Rev. 2022 Jun 22;122(12):11131-11168. (PMID: 35687869) |
| تواريخ الأحداث: | Date Created: 20240812 Latest Revision: 20240813 |
| رمز التحديث: | 20240813 |
| مُعرف محوري في PubMed: | PMC11308804 |
| DOI: | 10.1039/d4ya00217b |
| PMID: | 39131508 |
| قاعدة البيانات: | MEDLINE |
Full Text Finder | تدمد: | 2753-1457 |
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| DOI: | 10.1039/d4ya00217b |