دورية أكاديمية

Positive-tone crosslinked molecular resist based on acid-catalyzed depolymerization.

التفاصيل البيبلوغرافية
العنوان: Positive-tone crosslinked molecular resist based on acid-catalyzed depolymerization.
المؤلفون: Sharp, Brandon L., Narcross, Hannah L., Tolbert, Laren M., Henderson, Clifford L.
المصدر: Journal of Vacuum Science & Technology: Part B-Nanotechnology & Microelectronics; Nov2017, Vol. 35 Issue 6, p1-7, 7p
مصطلحات موضوعية: DEPOLYMERIZATION, CROSSLINKING (Polymerization), ACID catalysts, ELECTRON beam lithography, ELECTRON resists
مستخلص: Presented here is 1,1,1-tris(4-hydroxyphenyl) ethane (THPE)-2VE, a phenol-containing depolymerization resist that demonstrates a 248-nm deep ultraviolet sensitivity (dose-to-clear) of 3 mJ/cm² as well as a contrast ratio of 7.2 when formulated with 5 mol. % triphenyl sulfonium hexafluoroantimonate as photoacid generator. The 100 keV e-beam contrast curve shows a sensitivity of 24 µC/cm² for methyl isobutyl ketone (MIBK) development with a contrast ratio of 6.0. A sensitivity of 20 µC/cm² for 0.26 N tetra methyl ammonium hydroxide (TMAH) development and a contrast ratio of 10.3 was observed for 0.26 N TMAH development. THPE-2VE has been demonstrated to resolve features down to at least 35 nm lines with doses of 48 µC/cm² in MIBK development with a line edge roughness (LER) (3σ) value of 8.4 nm. In 0.26 N TMAH development, the material required an e-beam dose of 40 µC/cm² to pattern roughly 35 nm lines with an LER (3σ) value of 8.2 nm. This material shows improved sensitivity and shelf life compared to other depolymerization resist designs previously reported by our group. THPE-2VE has been demonstrated to resolve some of the smallest features reported to date with crosslinked depolymerization resists. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:21662746
DOI:10.1116/1.4991904