التفاصيل البيبلوغرافية
| العنوان: |
Encapsulating [Mo3S13]2− clusters in cationic covalent organic frameworks: enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst. |
| المؤلفون: |
Cheng, Yuan-Jie, Wang, Rui, Wang, Shan, Xi, Xiao-Juan, Ma, Lu-Fang, Zang, Shuang-Quan |
| المصدر: |
Chemical Communications; 12/14/2018, Vol. 54 Issue 96, p13563-13566, 4p |
| مصطلحات موضوعية: |
MOLYBDENUM sulfides, ENCAPSULATION (Catalysis), METAL-organic frameworks |
| مستخلص: |
We encapsulated anionic [Mo3S13]2− clusters in cationic COFs (EB-COF) to obtain the novel composite photocatalytic material Mo3S13@EB-COF. Comprehensive studies indicated that the Mo3S13@EB-COF was the product of a successful conversion of a homogeneous to a heterogeneous catalyst, and exhibited excellent stability and recyclability as well as a remarkable photocatalytic hydrogen evolution rate of 13 215 μmol g−1 h−1 under visible-light irradiation over the course of 18 hours. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
