التفاصيل البيبلوغرافية
| العنوان: |
Frontispiece: Directing Foldamer Self‐Assembly with a Cyclopropanoyl Cap. |
| المؤلفون: |
Lim, Danim, Kim, Hyunjoong, Gong, Jintaek, Eom, Jae‐Hoon, Yoon, Eunyoung, Driver, Russell W., Baik, Mu‐Hyun, Lee, Hee‐Seung |
| المصدر: |
Chemistry - A European Journal; 2/11/2019, Vol. 25 Issue 9, pN.PAG-N.PAG, 1p |
| مصطلحات موضوعية: |
MOLECULAR self-assembly, HYDROGEN bonding, DENSITY functional theory |
| مستخلص: |
Foldectures are typically formed from foldamers carrying a Boc group at the N‐terminus, which creates a network of N−H⋅⋅⋅O hydrogen bonds linking adjacent foldamers in head‐to‐tail packing modes. Although much less sterically demanding, cyclopropanoyl amides feature additionally an α‐proton known to form Cα−H⋅⋅⋅O hydrogen bonds with electron‐rich partners. Experimental and computational investigations of the tractable model system revealed that the strength of this secondary noncovalent interaction was sufficient to influence self‐assembly of foldamers. More information can be found in the Full Paper by R. W. Driver, M.‐H. Baik, and H.‐S. Lee et al. on page 2226. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
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