التفاصيل البيبلوغرافية
| العنوان: |
RhIII‐Catalyzed Straightforward Synthesis of Benzophenanthroline and Benzophenanthrolinone Derivatives using Anthranils. |
| المؤلفون: |
Biswas, Aniruddha, Sarkar, Souradip, Samanta, Rajarshi |
| المصدر: |
Chemistry - A European Journal; 2/26/2019, Vol. 25 Issue 12, p3000-3004, 5p |
| مصطلحات موضوعية: |
RHODIUM catalysts, BENZENE compounds, PHENANTHROLINE, KETONE derivatives, ANTHRANIL |
| مستخلص: |
An efficient pot‐economic and step‐economic RhIII‐catalyzed site‐selective direct amination/annulation strategy was developed for the synthesis of benzophenanthroline derivatives using quinoline N‐oxides and anthranils. The method was further extended to the synthesis of nitrogen‐containing extended π‐conjugated benzophenanthrolinone derivatives. Late‐stage functionalizations of cinchonidine and cinchophen derivatives and synthesis of a bioactive quinolino‐indole were achieved. An efficient pot‐economic and step‐economic RhIII‐catalyzed site‐selective direct amination/annulation strategy was developed for the synthesis of benzophenanthroline derivatives using quinoline N‐oxides and anthranils (see scheme). [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
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