دورية أكاديمية

Lithium Molybdate (Li2MoO3)−Sulfur Battery.

التفاصيل البيبلوغرافية
العنوان: Lithium Molybdate (Li2MoO3)−Sulfur Battery.
المؤلفون: Dharmasena, Ruchira R., Martinez‐Garcia, Alejandro, Atla, Veerendra, Akram, Muhammad Z., Sumanasekera, Gamini U., Sunkara, Mahendra K.
المصدر: Batteries & Supercaps; Mar2020, Vol. 3 Issue 3, p275-283, 9p
مستخلص: Here, we present a lithiated molybdate‐sulfur battery with practical energy density greater than 300 Wh kg−1. Electrochemically pre‐lithiated α‐MoO3 is prepared to form lithium molybdate anode which was tested against mesoporous titania coated sulfur cathode. A pouch cell with a capacity of 5 mAh made using pre‐lithiated lithium molybdate nanowires as anode and mesoporous TiO2 (titania) coated carbon‐sulfur cathode exhibited 1.4 V operating voltage and exhibited 620 Wh kg−1 capacity in the first cycle, dropped to ∼400 Wh kg−1 in 2nd cycle and 300 Wh kg−1 at 100th cycle. Various prelithiation studies indicate that electrochemical lithiation of MoO3 nanomaterials is crucial to make Li2MoO3 material suitable as anode. In situ electrochemical lithiation of MoO3 anode is introduced as a method to fabricate lithium molybdate (Li2MoO3)‐sulfur pouch cells in one step. [ABSTRACT FROM AUTHOR]
Copyright of Batteries & Supercaps is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
قاعدة البيانات: Complementary Index
الوصف
تدمد:25666223
DOI:10.1002/batt.201900176