التفاصيل البيبلوغرافية
| العنوان: |
Mixed Amidohalotantalates [Ta(NMe2)3X3]– (X = F, Cl). |
| المؤلفون: |
Petrov, P. A., Golubitskaya, E. A., Kompan'kov, N. B., Sukhikh, T. S., Sokolov, M. N. |
| المصدر: |
Russian Journal of Coordination Chemistry; Sep2020, Vol. 46 Issue 9, p593-599, 7p |
| مصطلحات موضوعية: |
TANTALUM, X-ray diffraction, FILES (Records) |
| مستخلص: |
The anionic tantalum complex (ItBuH)[Ta(NMe2)3Cl3] (I) is synthesized by the reaction of [Ta(NMe2)3Cl2]2 with N-heterocyclic carbene ItBu and is isolated as two crystalline modifications (Ia and Ib). Its fluoride analogue (ItBuH)[Ta(NMe2)3F3] (II) is synthesized by the reaction of Ta(NMe2)5 with (ItBuH)BF4. The structures of the complexes are determined by X-ray diffraction analysis (CIF files CCDC nos. 1977540 (Ia), 1977541 (Ib), and 1977542 (II)). [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
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