دورية أكاديمية

Photo- and electro-luminescence properties of two coumarin-triarylimidazole hybrid derivatives.

التفاصيل البيبلوغرافية
العنوان: Photo- and electro-luminescence properties of two coumarin-triarylimidazole hybrid derivatives.
المؤلفون: Wu, Xiaojing, Su, Ruige, Zhao, Yuling, Ma, Hailin, Liu, Xiaoxiao, Qian, Long, Han, Minghu, Su, Wenming, Yu, Tianzhi
المصدر: New Journal of Chemistry; 1/7/2022, Vol. 46 Issue 1, p212-220, 9p
مصطلحات موضوعية: QUANTUM efficiency, COUMARINS, THERMAL stability, THIN films, IMIDAZOLES, ELECTROLUMINESCENCE, DICHLOROMETHANE
مستخلص: Two coumarin-triarylimidazole hybrid derivatives with an N,N-diethylamine at the 7-position and a triaryl-substituted imidazole at the 3-position on the coumarin core, 3-(1-(4-(tert-butyl)phenyl)-4,5-diphenyl-1H-imidazol-2-yl)-7-(diethylamino)-2H-chromen-2-one (C-IM-Bu) and 3-(1-(4-cyanophenyl)-4,5-diphenyl-1H-imidazol-2-yl)-7-(diethylamino)-2H-chromen-2-one (C-IM-CN), were successfully synthesized for application in organic-light emitting devices. Their photophysical and electrochemical properties, thermal stability and electroluminescence properties were investigated. The results showed that these compounds have excellent thermal stability, and exhibit strong blue-green emission in dichloromethane solution and green emission in thin solid films. Further, the solution-processed doped devices based on the compounds were fabricated, in which the devices fabricated from C-IM-CN exhibited the best device performance with a turn-on voltage of 3.6 V, a maximum brightness of 6896 cd m−2, a maximum current efficiency of 6.39 cd A−1 and a maximum external quantum efficiency of 2.92%. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:11440546
DOI:10.1039/d1nj04676d