دورية أكاديمية

Nickel‐Catalyzed Ring Expansion of Cyclobutanones towards Indanones.

التفاصيل البيبلوغرافية
العنوان: Nickel‐Catalyzed Ring Expansion of Cyclobutanones towards Indanones.
المؤلفون: Chen, Tengyun, Wu, Yunkai, Han, Peilin, Gao, Jiqiang, Wu, Yuanqi, Zhao, Jinbo, Liang, Haotian, Liu, Yongsheng, Liu, Yu
المصدر: Helvetica Chimica Acta; Feb2022, Vol. 105 Issue 2, p1-7, 7p
مستخلص: Despite recent advances in catalytic ring‐opening/cross‐coupling process of o‐halogen tethered phenylcyclobutanones with other partners, single‐component ring expansion of such precursors towards 3‐methylindanones has not been disclosed. We present herein a nickel catalyzed C−C bond reconstruction sequence of o‐bromophenylcyclobutanones using H2O as hydrogen donor, leading to a series of indanones, which can be further converted into other benzene‐fused cyclic compounds. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:0018019X
DOI:10.1002/hlca.202100184