التفاصيل البيبلوغرافية
| العنوان: |
Coumarin Derivative Induced 3D Organo‐Silver(I) Complex with Tandem Hydrazine Detection and 4‐Nitrophenol Catalysis. |
| المؤلفون: |
Zhang, Jia‐Yuan, Hao, Hui‐Ping, Zhang, Yun‐Jie, Lv, Yu‐Guang, Wang, Xin‐Yu, Liu, Hong, Li, Shou‐Cong, Gao, Guang‐Gang |
| المصدر: |
Crystal Research & Technology; Mar2022, Vol. 57 Issue 3, p1-8, 8p |
| مستخلص: |
A new 3D organo‐silver(I) crystalline complex of [(MPC)4(CF3COO)8Ag10]n (MPC = 4‐methyl‐7‐propargyloxy coumarin) (JMSU‐Ag10) has been successfully synthesized. The crystal structure analysis shows that the 10‐core silver(I) cluster (Ag10) can be considered as the subunit of JMSU‐Ag10 with different Ag⋯$\cdots$Ag argentophilic interactions. By the protection of organic ligands and Ag⋯$\cdots$Ag interactions, the Ag10 subunits further compose a chain structure, and then the trifluoroacetate or the MPC ligands bridge the 1D silver(I) chains along different directions to form the 3D framework. Furthermore, JMSU‐Ag10 can be used to detect the hydrazine due to that the Ag+ ions can be reduced to Ag0 species with strong UV–vis absorption. Interestingly, the reduced JMSU‐Ag10 by hydrazine can be further used to catalyze the reduction of 4‐nitrophenol to form 4‐aminophenol. This work provides a new strategy for the design, synthesis, and the cyclic utilization of functional organo‐silver(I) crystalline materials. [ABSTRACT FROM AUTHOR] |
|
Copyright of Crystal Research & Technology is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| قاعدة البيانات: |
Complementary Index |
Full Text Finder