دورية أكاديمية

Modified ferroelectricity in multiferroic Ba4Nd2Fe2Nb8O30 ceramics via atmosphere treatment.

التفاصيل البيبلوغرافية
العنوان: Modified ferroelectricity in multiferroic Ba4Nd2Fe2Nb8O30 ceramics via atmosphere treatment.
المؤلفون: Li, Cheng, Hong, Jiang Sheng, Huang, Yu Hui, Ma, Xiao, Fu, Mao Sen, Li, Juan, Liu, Xiao Qiang, Wu, Yong Jun
المصدر: Journal of Materials Science: Materials in Electronics; Jul2022, Vol. 33 Issue 20, p16414-16424, 11p
مصطلحات موضوعية: TUNGSTEN bronze, FERROELECTRICITY, CERAMICS, HEAT treatment, HYSTERESIS loop, NEUTRON diffraction, LEAD titanate
مستخلص: Single-phase multiferroic Ba4Nd2Fe2Nb8O30 ceramics with the tetragonal tungsten bronze structure were synthesized. The dielectric, ferroelectric, and magnetic properties were systematically studied at room temperature, and the room-temperature multiferroic features were certified by the polarization–electric field hysteresis loops and magnetization-field curves in Ba4Nd2Fe2Nb8O30 ceramics. Interestingly, it was found that the ferroelectric polarization was enhanced by treating samples in non-oxidizing atmospheres, and the highest remnant polarization of 0.94 μC/cm2 can be found in the N2-annealed samples. The refined neutron powder diffraction results showed that the modified ferroelectricity was originated from the displacement of Fe3+/Nb5+ cations at B-sites rather than the oxygen vacancies. These results indicate that the heat treatment in controlled atmosphere is effective means to improve ferroelectricity in tetragonal tungsten bronze structure ceramics. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:09574522
DOI:10.1007/s10854-022-08535-9