دورية أكاديمية

Highly ordered graphite (HOPG) to hexagonal diamond (lonsdaleite) phase transition observed on picosecond time scales using ultrafast x-ray diffraction.

التفاصيل البيبلوغرافية
العنوان: Highly ordered graphite (HOPG) to hexagonal diamond (lonsdaleite) phase transition observed on picosecond time scales using ultrafast x-ray diffraction.
المؤلفون: Armstrong, Michael R., Radousky, Harry B., Austin, Ryan A., Tschauner, Oliver, Brown, Shaughnessy, Gleason, Arianna E., Goldman, Nir, Granados, Eduardo, Grivickas, Paulius, Holtgrewe, Nicholas, Kroonblawd, Matthew P., Lee, Hae Ja, Lobanov, Sergey, Nagler, Bob, Nam, Inhyuk, Prakapenka, Vitali, Prescher, Clemens, Reed, Evan J., Stavrou, Elissaios, Walter, Peter
المصدر: Journal of Applied Physics; 8/7/2022, Vol. 132 Issue 5, p1-10, 10p
مصطلحات موضوعية: PHASE transitions, X-ray diffraction, PYROLYTIC graphite, GRAPHITE, DIAMONDS, COHERENCE (Optics), ULTRASHORT laser pulses, PICOSECOND pulses
مستخلص: The response of rapidly compressed highly oriented pyrolytic graphite (HOPG) normal to its basal plane was investigated at a pressure of ∼80 GPa. Ultrafast x-ray diffraction using ∼100 fs pulses at the Materials Under Extreme Conditions sector of the Linac Coherent Light Source was used to probe the changes in crystal structure resulting from picosecond timescale compression at laser drive energies ranging from 2.5 to 250 mJ. A phase transformation from HOPG to a highly textured hexagonal diamond structure is observed at the highest energy, followed by relaxation to a still highly oriented, but distorted graphite structure following release. We observe the formation of a highly oriented lonsdaleite within 20 ps, subsequent to compression. This suggests that a diffusionless martensitic mechanism may play a fundamental role in phase transition, as speculated in an early work on this system, and more recent static studies of diamonds formed in impact events. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:00218979
DOI:10.1063/5.0085297