التفاصيل البيبلوغرافية
| العنوان: |
Alternating Terpolymers through Cyclopolymerization and Subsequent Orthogonal Functionalization. |
| المؤلفون: |
Gerdt, Philipp, Studer, Armido |
| المصدر: |
Angewandte Chemie International Edition; 9/26/2022, Vol. 61 Issue 39, p1-7, 7p |
| مصطلحات موضوعية: |
CYCLOPOLYMERIZATION, POLYMERIZATION, VINYL ethers, COPOLYMERIZATION, LIVING polymerization, ACYLATION, AMIDATION |
| مستخلص: |
A method for the synthesis of functionalized alternating copolymers by reversible deactivation radical polymerization was developed. Copolymerization by reversible addition–fragmentation chain transfer of hexenyl vinyl ether with a novel fluorinated divinyl monomer yields alternating cyclopolymers that can be chemoselectively modified by three distinct orthogonal functionalization reactions. Along the thiol‐ene click reaction and amidation, a third functionalization was achieved via NHC‐catalyzed transesterification or acylation resulting in a small library of ABC‐type alternating terpolymers. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
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