التفاصيل البيبلوغرافية
| العنوان: |
Optically Controlled Recovery and Recycling of Homogeneous Organocatalysts Enabled by Photoswitches. |
| المؤلفون: |
Qiu, Qianfeng, Sun, Zhenhuan, Joubran, Danielle, Li, Xiang, Wan, Joshua, Schmidt‐Rohr, Klaus, Han, Grace G. D. |
| المصدر: |
Angewandte Chemie; 3/20/2023, Vol. 135 Issue 13, p1-6, 6p |
| مصطلحات موضوعية: |
CATALYSTS recycling, CATALYST structure, SOLUBILITY, PROOF of concept, ENVIRONMENTAL economics |
| مستخلص: |
We address a critical challenge of recovering and recycling homogeneous organocatalysts by designing photoswitchable catalyst structures that display a reversible solubility change in response to light. Initially insoluble catalysts are UV‐switched to a soluble isomeric state, which catalyzes the reaction, then back‐isomerizes to the insoluble state upon completion of the reaction to be filtered and recycled. The molecular design principles that allow for the drastic solubility change over 10 times between the isomeric states, 87 % recovery by the light‐induced precipitation, and multiple rounds of catalyst recycling are revealed. This proof of concept will open up opportunities to develop highly recyclable homogeneous catalysts that are important for the synthesis of critical compounds in various industries, which is anticipated to significantly reduce environmental impact and costs. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
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