التفاصيل البيبلوغرافية
العنوان: |
Synthesis and Characterization of cis-[Ru(dppm)2(bta)]PF6 (bta– = 4,4,4-Trifluoro-1-Phenyl-1,3-Butanedionate). |
المؤلفون: |
Macêdo, R. R., Maia, P. I. S., Deflon, V. M., Miguel, G. F. G. F. de S., Machado, A. E. H., Von Poelhsitz, G. |
المصدر: |
Journal of Structural Chemistry; Apr2023, Vol. 64 Issue 4, p529-539, 11p |
مصطلحات موضوعية: |
ELEMENTAL analysis, ELECTRONIC structure, RUTHENIUM, X-ray diffraction, NUCLEAR magnetic resonance spectroscopy |
مستخلص: |
The title complex cis-[Ru(dppm)2(bta)]PF6, dppm = 1,1-bis(diphenylphosphino)methane; bta– = 4,4,4-trifluoro-1-phenyl-1,3-butanedionate, was prepared from the cis-[RuCl2(dppm)2] precursor in mild conditions. Elemental analysis, spectroscopy (FTIR, 1H, 31P{1H} and 19F{1H} NMR) as well as single-crystal X-ray diffraction were used to characterize the new complex. Electronic structure of the complex was described utilizing TD-DFT analysis. All data indicate a good degree of purity, a cis arrangement for the diphosphines and a distorted geometry for the ruthenium center. [ABSTRACT FROM AUTHOR] |
|
Copyright of Journal of Structural Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
قاعدة البيانات: |
Complementary Index |