التفاصيل البيبلوغرافية
| العنوان: |
Rotaxane Formation of Multicyclic Polydimethylsiloxane in a Silicone Network: A Step toward Constructing "Macro‐Rotaxanes" from High‐Molecular‐Weight Axle and Wheel Components. |
| المؤلفون: |
Ebe, Minami, Soga, Asuka, Fujiwara, Kaiyu, Ree, Brian J., Marubayashi, Hironori, Hagita, Katsumi, Imasaki, Atsushi, Baba, Miru, Yamamoto, Takuya, Tajima, Kenji, Deguchi, Tetsuo, Jinnai, Hiroshi, Isono, Takuya, Satoh, Toshifumi |
| المصدر: |
Angewandte Chemie International Edition; 8/28/2023, Vol. 62 Issue 35, p1-11, 11p |
| مصطلحات موضوعية: |
SILICONES, DIMETHYLPOLYSILOXANES, CYCLOPOLYMERIZATION, POLYMER networks, AXLES, POLYDIMETHYLSILOXANE, WHEELS |
| مستخلص: |
Rotaxanes consisting of a high‐molecular‐weight axle and wheel components (macro‐rotaxanes) have high structural freedom, and are attractive for soft‐material applications. However, their synthesis remains underexplored. Here, we investigated macro‐rotaxane formation by the topological trapping of multicyclic polydimethylsiloxanes (mc‐PDMSs) in silicone networks. mc‐PDMS with different numbers of cyclic units and ring sizes was synthesized by cyclopolymerization of a α,ω‐norbornenyl‐functionalized PDMS. Silicone networks were prepared in the presence of 10–60 wt % mc‐PDMS, and the trapping efficiency of mc‐PDMS was determined. In contrast to monocyclic PDMS, mc‐PDMSs with more cyclic units and larger ring sizes can be quantitatively trapped in the network as macro‐rotaxanes. The damping performance of a 60 wt % mc‐PDMS‐blended silicone network was evaluated, revealing a higher tan δ value than the bare PDMS network. Thus, macro‐rotaxanes are promising as non‐leaching additives for network polymers. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
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