التفاصيل البيبلوغرافية
| العنوان: |
Swift C–C bond insertion by a 12-electron palladium(0) surrogate. |
| المؤلفون: |
Breitwieser, Kevin, Dankert, Fabian, Grünwald, Annette, Mayer, Paula R., Heinemann, Frank W., Munz, Dominik |
| المصدر: |
Chemical Communications; 10/18/2023, Vol. 59 Issue 81, p12104-12107, 4p |
| مصطلحات موضوعية: |
PALLADIUM, ORBITAL hybridization, CYCLOPROPENE, BENZONITRILE, BIPHENYLENE, RHODIUM catalysts, CARBENE synthesis |
| مستخلص: |
The selective activation of C–C bonds holds vast promise for catalysis. So far, research has been primarily directed at rhodium and nickel under harsh reaction conditions. Herein, we report C–C insertion reactions of a 12-electron palladium(0) surrogate stabilized by a cyclic(alkyl)(amino) carbene (CAAC) ligand. Benzonitrile (1), biphenylene (2), benzocyclobutenone (3), and naphtho[b]cyclopropene (4) were studied. These substrates allow elucidation of the effect of ring strain as well as hybridization encompassing sp3, sp2 and sp hybridized carbon atoms. All reactions proceed quantitatively at or below room temperature. This work therefore outlines perspectives for mild C–C bond functionalization catalysis. [ABSTRACT FROM AUTHOR] |
|
Copyright of Chemical Communications is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| قاعدة البيانات: |
Complementary Index |
