التفاصيل البيبلوغرافية
| العنوان: |
Thermal conductivity and fractal texture formation in β-Si3N4/polyvinylidene fluoride composites. |
| المؤلفون: |
Munakata, Fumio, Ogiya, Taito, Konemura, Ryo, Sato, Yoshihiro, Kitani, Suguru, Kawaji, Hitoshi |
| المصدر: |
Journal of Applied Physics; 11/14/2023, Vol. 134 Issue 18, p1-10, 10p |
| مصطلحات موضوعية: |
MULTIFRACTALS, MATERIALS texture, THERMAL conductivity, POLYVINYLIDENE fluoride, FRACTAL dimensions, GROUP formation, CLUSTERING of particles |
| مستخلص: |
Additive incorporation into polymers can enhance properties, such as the dielectric constant and thermal conductivity. The improved properties of polymer composites have largely been attributed to aggregate and network formation, but the influence of material texture requires clarification. Herein, the relationship between the texture of composite materials and thermal conductivity was investigated based on the fractal nature of composites consisting of polyvinylidene fluoride (PVDF) with β-Si3N4 (SN) as a high-thermal-conductivity filler. The SN particle groups were found to contribute to the formation of thermal conduction paths in the composite material and, thus, improve the thermal conductivity. The characteristics of the particle group clusters involved in SN particle percolation were elucidated by analyzing the interactions between multiple particles as a function of the amount of each fractal dimension. In addition, based on the statistical relationships obtained from the multifractal analysis, the strengths of the interactions between particles during thermal conduction path formation were estimated. Overall, the texture of the SN/PVDF material was characterized by local particle group formation (self-assembly) and subsequent global particle group network construction (self-organization), depending on the amount of SN added. These results suggest that multifractal dimensions can be used as material design indices for the texture of polymer composites. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
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