التفاصيل البيبلوغرافية
| العنوان: |
Removal of cerium ions by Amino Cyclohexyl Phosphonic Acid (ACHPA) intercalated into layered double hydroxide (Ni/Al-LDH). |
| المؤلفون: |
Kadari, M., Makhlouf, M., Kaid, M., Benmaamar, Z., Villemin, D. |
| المصدر: |
Advances in Materials & Processing Technologies; Dec2023, Vol. 9 Issue 4, p2017-2029, 13p |
| مصطلحات موضوعية: |
LAYERED double hydroxides, CERIUM, HYBRID materials, ADSORPTION isotherms, ORGANIC solvents, LIQUID-liquid extraction, PHOSPHONIC acids |
| مستخلص: |
Amino phosphonic acids are good heavy metal extractants for liquid–liquid extraction, but this method requires the use of an organic solvent, which is itself a pollutant. The incorporation of these acids in solid supports gave us the opportunity to find a solution to this problem. The synthesis of the new material by incorporation of Amino-Cyclo-Hexyl Phosphonic Acid into the interlayer space of the Ni/Al-LDH, designated as Ni/Al-ACHPA, was carried out by the coprecipitation method and anion exchange. The new hybrid material was characterised by FTIR, XRD and BET. The results obtained show that ACHPA is well intercalated in LDH. The adsorption performance of the new hybrid material towards the ions of Cerium Ce+3, has been investigated under different parameters. Under optimal conditions, where the highest recovery (75%) was obtained at pH 6 using 0.1 g of adsorbent (Ni/Al-ACHPA) for less than 30 min of agitation. The modelling results of the kinetics indicate that the Ce+3 adsorption process mechanism is well fitted by a pseudo-second order equation with a high regression coefficient (R2 = 99%) and the adsorption isotherms were fitting well with the Freundlich isotherm model. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
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