التفاصيل البيبلوغرافية
| العنوان: |
Selective dehydrogenation of ammonia borane to polycondensated BN rings catalysed by ruthenium olefin complexes. |
| المؤلفون: |
Himmelbauer, Daniel, Müller, Fabian, Schweinzer, Clara, Casas, Fernando, Pribanic, Bruno, Le Corre, Grégoire, Thöny, Debora, Trincado, Monica, Grützmacher, Hansjörg |
| المصدر: |
Chemical Communications; 1/21/2024, Vol. 60 Issue 7, p885-888, 4p |
| مصطلحات موضوعية: |
RUTHENIUM compounds, BORANES, DEHYDROGENATION, AMMONIA, BORON nitride, BORAZINE, OLIGOMERS, RUTHENIUM catalysts |
| مستخلص: |
Dehydrogenation of ammonia borane to well-defined products is an important but challenging reaction. A dinuclear ruthenium complex with a Ru–Ru bond bearing a diazadiene (dad) unit and olefins as non-innocent ligands catalyzes the highly selective formation of conjugated polycondensed borazine oligomers (BxNxHy), predominantly B21N21H18, the BN analogue of superbenzene. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
