التفاصيل البيبلوغرافية
| العنوان: |
N-Alkyl substituted triazenide-bridged homoleptic iron(II) dimers with an exceptionally short Fe–Fe bond. |
| المؤلفون: |
Soussi, Khaled, Jeanneau, Erwann, Maldivi, Pascale, Clémancey, Martin, Latour, Jean-Marc, Khrouz, Lhoussain, Lorentz, Chantal, Daniele, Stéphane, Mishra, Shashank |
| المصدر: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 1/28/2024, Vol. 53 Issue 4, p1439-1444, 6p |
| مصطلحات موضوعية: |
TRANSITION metal complexes, DIMERS, IRON, TRANSITION metals, LIGANDS (Chemistry) |
| مستخلص: |
Dinuclear transition metal complexes with direct metal–metal interactions have the potential to generate unique reactivities and properties. Using asymmetric triazine ligands HN3tBuR (R = Et, iPr, nBu) featuring different alkyl substituents at 1,3-N centers, we report here the first rational synthesis of 'tetragonal lantern' type Fe(II) triazenides [Fe2(N3tBuR)4] [R = Et (1), iPr (2), nBu (3)] having an exceptionally short Fe–Fe distance (2.167–2.174 Å). Unlike the previously reported lantern structures with related amidinate or guanidinate ligands, highly air-sensitive 1–3 show a lower spin ground state, as indicated by Mössbauer, 1H NMR and DFT studies. [ABSTRACT FROM AUTHOR] |
|
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| قاعدة البيانات: |
Complementary Index |
